DOI: 10.1002/ange.19921041215. Neuer Mn‐O‐Clustertyp mit kettenförmiger Mn<sub>4</sub>‐Einheit — Bezug zum Reaktionszentrum des Photosystems II

Neuer Mn‐O‐Clustertyp mit kettenförmiger Mn4‐Einheit — Bezug zum Reaktionszentrum des Photosystems II

10.1002/ange.19921041215

Crossref journal-article

Wiley

Angewandte Chemie (311)

Abstract

Aus zwei Mn2(μ‐O)2‐Einheiten, die wiederum über zwei Oxobrücken verknüpft sind, besteht der Clusterkern von 1 (Strukturbild rechts, Je zwei Bipyridin(bpy)‐Liganden an Mn1 und Mn4 weggelassen). Dessen Mn‐Mn‐Abstände und magnetische Eigenschaften deuten an, daß der Cluster ein Modell für das Reaktionszenturm der Sauerstofferzeugung in pflanzen sein könnte. Ob die Mn4‐Anordnung im natürlich vorkommenden Enzym kettenförmig oder Teil einer Cubanstruktur ist, bleibt jedoch weiter offen.magnified image

Bibliography

Philouze, C., Blondin, G., MÃ©nage, S., Auger, N., Girerd, J., Vigner, D., Lance, M., & Nierlich, M. (1992). Neuer MnâOâClustertyp mit kettenfÃ¶rmiger Mn4âEinheit â Bezug zum Reaktionszentrum des Photosystems II. Angewandte Chemie, 104(12), 1634â1636. Portico.

Authors 8

Christian Philouze (first)
Geneviève Blondin (additional)
Stéphane Ménage (additional)
Nathalie Auger (additional)
Jean‐Jacques Girerd (additional)
Daniel Vigner (additional)
Monique Lance (additional)
Martine Nierlich (additional)

References 37 Referenced 6

10.1021/ar00010a005
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(c)A. W.Rutherford J.‐L.Zimmermann A.BoussacinThe Photosystems: Structure Function and Molecular Biology(Hrsg.: J. Barber) 1992 S.179. (10.1016/B978-0-444-89440-3.50014-X)
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Kristalldaten: triklin P1 a=13.557(5) b= 21.885(9) c= 26.294(14) Å α = 67.63(4) β = 85.41(4) γ = 73.82(4)° V= 6926 Å3 Z= 4 Aufgrund der niedrigen Symmetrie und der Anzahl der Atome deren Position verfeinert werden muß (312) führte der Datensatz nur zu einemR‐Wert von 0.012. Wir werden einen umfangreicheren Datensatz aufnehmen.
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Dates

Type	When
Created	18 years, 1 month ago (July 16, 2007, 2:20 a.m.)
Deposited	1 year, 10 months ago (Oct. 7, 2023, 1:07 p.m.)
Indexed	1 year, 10 months ago (Oct. 31, 2023, 1:19 a.m.)
Issued	32 years, 9 months ago (Dec. 1, 1992)
Published	32 years, 9 months ago (Dec. 1, 1992)
Published Online	19 years, 7 months ago (Jan. 13, 2006)
Published Print	32 years, 9 months ago (Dec. 1, 1992)

Funders 0

None

BibTeX

@article{Philouze_1992, title={Neuer Mn‐O‐Clustertyp mit kettenförmiger Mn4‐Einheit — Bezug zum Reaktionszentrum des Photosystems II}, volume={104}, ISSN={1521-3757}, url={http://dx.doi.org/10.1002/ange.19921041215}, DOI={10.1002/ange.19921041215}, number={12}, journal={Angewandte Chemie}, publisher={Wiley}, author={Philouze, Christian and Blondin, Geneviève and Ménage, Stéphane and Auger, Nathalie and Girerd, Jean‐Jacques and Vigner, Daniel and Lance, Monique and Nierlich, Martine}, year={1992}, month=dec, pages={1634–1636} }

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