DOI: 10.1002/aic.690340312. Stability and tensile strength of liquids exhibiting density maxima

Stability and tensile strength of liquids exhibiting density maxima

10.1002/aic.690340312

Crossref journal-article

Wiley

AIChE Journal (311)

Abstract

AbstractIf a given liquid exhibits a density maximum anywhere in its phase diagram, thermodynamic consistency dictates that such a point cannot be isolated: a density maxima locus must necessarily exist. For a fluid that does not also exhibit density minima, the pressure‐temperature projection of such a locus is negatively sloped, and can only end at a stability limit. There exist two thermodynamically consistent ways in which such an intersection can occur, and they correspond, respectively, to the highest and lowest possible temperatures at which a liquid can exhibit a negative coefficient of thermal expansion. These theoretical predictions are confirmed by experimental observations. The existence of density anomalies anywhere in a liquid's phase diagram is shown to have a profound influence in determining the shape of such a fluid's stability boundary.

Bibliography

Debenedetti, P. G., & DâAntonio, M. C. (1988). Stability and tensile strength of liquids exhibiting density maxima. AIChE Journal, 34(3), 447â455. Portico.

Authors 2

P. G. Debenedetti (first)
M. C. D'Antonio (additional)

References 37 Referenced 37

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Dates

Type	When
Created	21 years, 1 month ago (June 23, 2004, 9:50 a.m.)
Deposited	1 year, 10 months ago (Oct. 20, 2023, 7:24 p.m.)
Indexed	1 year, 6 months ago (Feb. 11, 2024, 2:20 a.m.)
Issued	37 years, 5 months ago (March 1, 1988)
Published	37 years, 5 months ago (March 1, 1988)
Published Online	21 years, 2 months ago (June 17, 2004)
Published Print	37 years, 5 months ago (March 1, 1988)

Funders 0

None

BibTeX

@article{Debenedetti_1988, title={Stability and tensile strength of liquids exhibiting density maxima}, volume={34}, ISSN={1547-5905}, url={http://dx.doi.org/10.1002/aic.690340312}, DOI={10.1002/aic.690340312}, number={3}, journal={AIChE Journal}, publisher={Wiley}, author={Debenedetti, P. G. and D’Antonio, M. C.}, year={1988}, month=mar, pages={447–455} }

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