Abstract
AbstractExperimental measurements have been conducted of Knudsen diffusion through a model porous medium fabricated by the pelleting of monodisperse silica spheres. Tortuosity factors for this random‐assemblage‐of‐spheres porous solid are calculated and compared with values obtained from both theory and measurements made in the bulk diffusion regime. Evidence is presented to support the use of a mean pore radius calculated as twice the ratio of pore volume to surface area, as opposed to values obtained from mercury porosimetry or sorption isotherm analysis.
References
17
Referenced
81
10.1002/aic.690290415
10.1021/i160026a003
10.1088/0508-3443/11/8/303
10.1016/0021-9797(74)90265-3
10.1063/1.439488
10.1002/cjce.5450470206
10.1021/ie50545a016
- Huizenga D. G. “Knudsen Diffusion in Beds of Monodisperse Silica Spheres ” MS Thesis Montana State Univ. Bozeman (1984).
{'key': 'e_1_2_1_10_1', 'first-page': '21', 'volume-title': 'The Colloid Chemistry of Silica and Silicates', 'author': 'Iler R. K.', 'year': '1955'}
/ The Colloid Chemistry of Silica and Silicates by Iler R. K. (1955){'key': 'e_1_2_1_11_1', 'first-page': '73', 'article-title': 'The Laws of Molecular Flow and Viscous Flow of Gases through Tubes', 'volume': '28', 'author': 'Knudsen M.', 'year': '1928', 'journal-title': 'Annal. Phys.'}
/ Annal. Phys. / The Laws of Molecular Flow and Viscous Flow of Gases through Tubes by Knudsen M. (1928){'key': 'e_1_2_1_12_1', 'first-page': '62', 'volume-title': 'Introduction to Powder Surface Area', 'author': 'Lowell S.', 'year': '1979'}
/ Introduction to Powder Surface Area by Lowell S. (1979)10.1016/0021-9797(71)90121-4
10.1002/aic.690040322
{'key': 'e_1_2_1_15_1', 'first-page': '41', 'volume-title': 'Mass Transfer in Heterogenous Catalysis', 'author': 'Satterfield C. N.', 'year': '1970'}
/ Mass Transfer in Heterogenous Catalysis by Satterfield C. N. (1970){'key': 'e_1_2_1_16_1', 'first-page': '13', 'volume-title': 'Proc. 10th IASTED Symp. Appl. Modeling and Simulation', 'author': 'Smith D. M.', 'year': '1984'}
/ Proc. 10th IASTED Symp. Appl. Modeling and Simulation by Smith D. M. (1984)10.1016/0021-9797(68)90272-5
10.1002/aic.690290118
Dates
Type | When |
---|---|
Created | 21 years, 1 month ago (June 23, 2004, 10:06 a.m.) |
Deposited | 1 year, 10 months ago (Oct. 21, 2023, 12:08 p.m.) |
Indexed | 1 day, 15 hours ago (Aug. 20, 2025, 9:13 a.m.) |
Issued | 39 years, 7 months ago (Jan. 1, 1986) |
Published | 39 years, 7 months ago (Jan. 1, 1986) |
Published Online | 21 years, 2 months ago (June 17, 2004) |
Published Print | 39 years, 7 months ago (Jan. 1, 1986) |
@article{Huizenga_1986, title={Knudesen diffusion in random assemblages of uniform spheres}, volume={32}, ISSN={1547-5905}, url={http://dx.doi.org/10.1002/aic.690320102}, DOI={10.1002/aic.690320102}, number={1}, journal={AIChE Journal}, publisher={Wiley}, author={Huizenga, D. G. and Smith, D. M.}, year={1986}, month=jan, pages={1–6} }