DOI: 10.1002/aenm.201200370. Unexpected Improved Performance of ALD Coated LiCoO<sub>2</sub>/Graphite Li‐Ion Batteries

Unexpected Improved Performance of ALD Coated LiCoO2/Graphite Li‐Ion Batteries

10.1002/aenm.201200370

Crossref journal-article

Wiley

Advanced Energy Materials (311)

Abstract

AbstractThe performance of Al2O3 atomic layer deposition (ALD) coatings for LiCoO2/natural graphite (LCO/NG) batteries is investigated, where various permutations of the electrodes are coated in a full battery. Coating both electrodes with ∼1 nm of alumina as well as coating only the LCO (positive electrode) enables improved performance when cycling at high voltage, where the LCO is known to degrade. However, we found that coating only the NG (negative electrode) also improves the performance of the whole battery when cycling at high voltage. Under these conditions, the uncoated LCO (positive electrode) should degrade quickly, and the NG should be unaffected. A variety of characterization techniques show the surface reactions that occur on the negative electrode and positive electrode are related, resulting in the enhanced performance of the uncoated LCO.

Bibliography

Jung, Y. S., Lu, P., Cavanagh, A. S., Ban, C., Kim, G., Lee, S., George, S. M., Harris, S. J., & Dillon, A. C. (2012). Unexpected Improved Performance of ALD Coated LiCoO2/Graphite LiâIon Batteries. Advanced Energy Materials, 3(2), 213â219. Portico.

Authors 9

Yoon Seok Jung (first)
Peng Lu (additional)
Andrew S. Cavanagh (additional)
Chunmei Ban (additional)
Gi‐Heon Kim (additional)
Se‐Hee Lee (additional)
Steven M. George (additional)
Stephen J. Harris (additional)
Anne C. Dillon (additional)

References 30 Referenced 219

10.1038/451652a
10.1021/cm901452z
10.1021/cr9003314
Idaho National Laboratory website Battery Test Manual for Plug‐In Hybrid Electric Vehicle;http://www.inl.gov(accessed August 2012).
10.1016/S0378-7753(00)00431-6
10.1016/j.jpowsour.2008.08.062
10.1149/1.3258274
10.1002/adma.200903951
10.1021/cr030203g
10.1002/1521-3773(20010917)40:18<3367::AID-ANIE3367>3.0.CO;2-A
10.1002/anie.200250452
10.1016/j.electacta.2005.11.015
10.1021/nl1030198
10.1002/cphc.201000158
10.1002/adfm.201002576
10.1002/aenm.201100750
10.1002/adma.201102568
10.1021/nl202088h
10.1016/0039-6028(95)90033-0
10.1021/cr900056b
10.1149/1.1870752
10.1149/1.1836981
10.1149/1.3481711
10.1021/nl052453d
10.1016/S0378-7753(02)00267-7
10.1149/1.2964220
10.1002/adfm.201101123
10.1021/jp9514279
10.1021/jp962815t
10.1021/cm900862v

Dates

Type	When
Created	12 years, 11 months ago (Sept. 13, 2012, 2:35 a.m.)
Deposited	1 year, 10 months ago (Oct. 11, 2023, 5:25 p.m.)
Indexed	9 hours, 27 minutes ago (Aug. 21, 2025, 2:06 p.m.)
Issued	12 years, 11 months ago (Sept. 13, 2012)
Published	12 years, 11 months ago (Sept. 13, 2012)
Published Online	12 years, 11 months ago (Sept. 13, 2012)
Published Print	12 years, 6 months ago (Feb. 1, 2013)

Funders 0

None

BibTeX

@article{Jung_2012, title={Unexpected Improved Performance of ALD Coated LiCoO2/Graphite Li‐Ion Batteries}, volume={3}, ISSN={1614-6840}, url={http://dx.doi.org/10.1002/aenm.201200370}, DOI={10.1002/aenm.201200370}, number={2}, journal={Advanced Energy Materials}, publisher={Wiley}, author={Jung, Yoon Seok and Lu, Peng and Cavanagh, Andrew S. and Ban, Chunmei and Kim, Gi‐Heon and Lee, Se‐Hee and George, Steven M. and Harris, Stephen J. and Dillon, Anne C.}, year={2012}, month=sep, pages={213–219} }

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