DOI: 10.1002/adsc.201000781. N‐Heterocyclic Carbene Piano‐Stool Iron Complexes as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives

N‐Heterocyclic Carbene Piano‐Stool Iron Complexes as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives

10.1002/adsc.201000781

Crossref journal-article

Wiley

Advanced Synthesis & Catalysis (311)

Abstract

AbstractHydrosilylation with well defined piano‐stool iron(II) complexes bearing both N‐heterocyclic carbene and cyclopentadienyl ligands was accomplished with both aldehydes and ketones. Typically, the reduction of aldehydes exhibited good activities (full reduction at 30 °C in 3 h), whereas for ketones, the reaction need 16 h at 70 °C to obtain good conversions. Of notable interest is the use of visible light irradiation to generate one of the active catalyst.

Bibliography

Jiang, F., BÃ©zier, D., Sortais, J., & Darcel, C. (2011). NâHeterocyclic Carbene PianoâStool Iron Complexes as Efficient Catalysts for Hydrosilylation of Carbonyl Derivatives. Advanced Synthesis & Catalysis, 353(2â3), 239â244. Portico.

Authors 4

Fan Jiang (first)
David Bézier (additional)
Jean‐Baptiste Sortais (additional)
Christophe Darcel (additional)

References 83 Referenced 113

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10.1016/j.jorganchem.2005.07.066
Some representative reviews:
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10.1002/anie.200503858
10.1002/1521-3757(20020415)114:8<1342::AID-ANGE1342>3.0.CO;2-A
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10.1021/cr040664h
10.1002/9783527623273
10.1002/ange.200800012
10.1002/anie.200800012
10.1039/b801794h
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10.1021/ja046753t
10.1039/B617388H
10.1021/ol7021802
10.1016/j.tetlet.2007.11.002
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{'key': 'e_1_2_4_70_2', 'first-page': '10', 'author': 'Muraoka T.', 'year': '2010', 'journal-title': 'Organometallics'} / Organometallics by Muraoka T. (2010)
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10.1016/0022-328X(91)86067-Z
10.1016/0022-328X(92)80027-U

Dates

Type	When
Created	14 years, 7 months ago (Jan. 19, 2011, 9:31 a.m.)
Deposited	2 years ago (Sept. 1, 2023, 8:46 p.m.)
Indexed	1 year ago (Aug. 26, 2024, 3:13 a.m.)
Issued	14 years, 7 months ago (Jan. 19, 2011)
Published	14 years, 7 months ago (Jan. 19, 2011)
Published Online	14 years, 7 months ago (Jan. 19, 2011)
Published Print	14 years, 6 months ago (Feb. 11, 2011)

Funders 0

None

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