Lewis Basic Ionic Liquids‐Catalyzed Conversion of Carbon Dioxide to Cyclic Carbonates
10.1002/adsc.201000239
Crossref journal-article
Wiley
Advanced Synthesis & Catalysis (311)
Abstract

AbstractA series of easily prepared Lewis basic ionic liquids were developed for cyclic carbonate synthesis from epoxide and carbon dioxide at low pressure without utilization of any organic solvents or additives. Notably, quantitative yields together with excellent selectivity were attained when 1,8‐diazabicyclo[5.4.0]undec‐7‐enium chloride ([HDBU]Cl) was used as a catalyst. Furthermore, the catalyst could be recycled over five times without appreciable loss of catalytic activity. The effects of the catalyst structure and various reaction parameters on the catalytic performance were investigated in detail. This protocol was found to be applicable to a variety of epoxides producing the corresponding cyclic carbonates in high yields and selectivity. Therefore, this solvent‐free process thus represents an environmentally friendly example for the catalytic conversion of carbon dioxide into value‐added chemicals by employing Lewis basic ionic liquids as catalyst. A possible catalytic cycle for the hydrogen bond‐assisted ring‐opening of epoxide and activation of carbon dioxide induced by the nucleophilic tertiary nitrogen of the ionic liquid was also proposed.

Bibliography

Yang, Z., He, L., Miao, C., & Chanfreau, S. (2010). Lewis Basic Ionic Liquids‐Catalyzed Conversion of Carbon Dioxide to Cyclic Carbonates. Advanced Synthesis & Catalysis, 352(13), 2233–2240. Portico.

Authors 4
  1. Zhen‐Zhen Yang (first)
  2. Liang‐Nian He (additional)
  3. Cheng‐Xia Miao (additional)
  4. Sébastien Chanfreau (additional)
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Dates
Type When
Created 15 years ago (Aug. 22, 2010, 6:29 a.m.)
Deposited 1 year, 10 months ago (Oct. 8, 2023, 7:56 a.m.)
Indexed 3 days, 4 hours ago (Aug. 27, 2025, noon)
Issued 15 years ago (Aug. 20, 2010)
Published 15 years ago (Aug. 20, 2010)
Published Online 15 years ago (Aug. 20, 2010)
Published Print 14 years, 11 months ago (Sept. 10, 2010)
Funders 0

None

@article{Yang_2010, title={Lewis Basic Ionic Liquids‐Catalyzed Conversion of Carbon Dioxide to Cyclic Carbonates}, volume={352}, ISSN={1615-4169}, url={http://dx.doi.org/10.1002/adsc.201000239}, DOI={10.1002/adsc.201000239}, number={13}, journal={Advanced Synthesis & Catalysis}, publisher={Wiley}, author={Yang, Zhen‐Zhen and He, Liang‐Nian and Miao, Cheng‐Xia and Chanfreau, Sébastien}, year={2010}, month=aug, pages={2233–2240} }