DOI: 10.1002/adsc.200700422. Suzuki‐ and Heck‐Type Cross‐Coupling with Palladium Nanoparticles Immobilized on Spherical Polyelectrolyte Brushes

Suzuki‐ and Heck‐Type Cross‐Coupling with Palladium Nanoparticles Immobilized on Spherical Polyelectrolyte Brushes

10.1002/adsc.200700422

Crossref journal-article

Wiley

Advanced Synthesis & Catalysis (311)

Abstract

AbstractWe report on a systematic study of the use of palladium nanoparticles immobilized on spherical polyelectrolyte brushes – Pd@SPB – for Heck‐ and Suzuki‐type coupling reactions. The spherical polyelectrolyte brush particles serving as carriers for the palladium nanoparticles consist of a solid polystyrene core with a radius of 46 nm onto which long chains of cationic polyelectrolytes are grafted. The palladium nanoparticles have directly been generated within this brush layer and the stabilization of the nanoparticles is effected by the colloidal carriers, no further surface stabilization is necessary. We demonstrate that these composite particles present robust catalysts for the Heck‐ and Suzuki‐type coupling reactions. This was shown by carrying out the Suzuki‐ and Heck‐type coupling reactions at relatively low temperatures (Suzuki reaction: 50 °C, Heck reaction: 70 °C). We demonstrate that the catalytic composite particles are not changed by these reaction conditions and retain their full activity for at least four runs. The yields obtained for both reactions are good to excellent. The mild operation conditions of the palladium nanoparticles are traced back to the absence of surface stabilization. Further mechanistic implications are discussed.

Bibliography

Proch, S., Mei, Y., Villanueva, J. M. R., Lu, Y., Karpov, A., Ballauff, M., & Kempe, R. (2008). Suzukiâ and HeckâType CrossâCoupling with Palladium Nanoparticles Immobilized on Spherical Polyelectrolyte Brushes. Advanced Synthesis & Catalysis, 350(3), 493â500. Portico.

Authors 7

S. Proch (first)
Y. Mei (additional)
J. M. Rivera Villanueva (additional)
Y. Lu (additional)
A. Karpov (additional)
M. Ballauff (additional)
R. Kempe (additional)

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Dates

Type	When
Created	17 years, 6 months ago (Feb. 8, 2008, 8:46 a.m.)
Deposited	1 year, 9 months ago (Nov. 14, 2023, 3:51 p.m.)
Indexed	1 week, 6 days ago (Aug. 22, 2025, 12:48 a.m.)
Issued	17 years, 6 months ago (Feb. 19, 2008)
Published	17 years, 6 months ago (Feb. 19, 2008)
Published Online	17 years, 6 months ago (Feb. 19, 2008)
Published Print	17 years, 6 months ago (Feb. 22, 2008)

Funders 0

None

BibTeX

@article{Proch_2008, title={Suzuki‐ and Heck‐Type Cross‐Coupling with Palladium Nanoparticles Immobilized on Spherical Polyelectrolyte Brushes}, volume={350}, ISSN={1615-4169}, url={http://dx.doi.org/10.1002/adsc.200700422}, DOI={10.1002/adsc.200700422}, number={3}, journal={Advanced Synthesis & Catalysis}, publisher={Wiley}, author={Proch, S. and Mei, Y. and Villanueva, J. M. Rivera and Lu, Y. and Karpov, A. and Ballauff, M. and Kempe, R.}, year={2008}, month=feb, pages={493–500} }

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