DOI: 10.1002/adma.201702069. Three‐State Ferroelastic Switching and Large Electromechanical Responses in PbTiO<sub>3</sub> Thin Films

Three‐State Ferroelastic Switching and Large Electromechanical Responses in PbTiO3 Thin Films

10.1002/adma.201702069

Crossref journal-article

Wiley

Advanced Materials (311)

Abstract

Leveraging competition between energetically degenerate states to achieve large field‐driven responses is a hallmark of functional materials, but routes to such competition are limited. Here, a new route to such effects involving domain‐structure competition is demonstrated, which arises from strain‐induced spontaneous partitioning of PbTiO3 thin films into nearly energetically degenerate, hierarchical domain architectures of coexisting c/a and a1/a2 domain structures. Using band‐excitation piezoresponse force microscopy, this study manipulates and acoustically detects a facile interconversion of different ferroelastic variants via a two‐step, three‐state ferroelastic switching process (out‐of‐plane polarized c+ → in‐plane polarized a → out‐of‐plane polarized c− state), which is concomitant with large nonvolatile electromechanical strains (≈1.25%) and tunability of the local piezoresponse and elastic modulus (>23%). It is further demonstrated that deterministic, nonvolatile writing/erasure of large‐area patterns of this electromechanical response is possible, thus showing a new pathway to improved function and properties.

Bibliography

Damodaran, A. R., Pandya, S., Agar, J. C., Cao, Y., Vasudevan, R. K., Xu, R., Saremi, S., Li, Q., Kim, J., McCarter, M. R., Dedon, L. R., Angsten, T., Balke, N., Jesse, S., Asta, M., Kalinin, S. V., & Martin, L. W. (2017). ThreeâState Ferroelastic Switching and Large Electromechanical Responses in PbTiO3 Thin Films. Advanced Materials, 29(37). Portico.

Authors 17

Anoop R. Damodaran (first)
Shishir Pandya (additional)
Josh C. Agar (additional)
Ye Cao (additional)
Rama K. Vasudevan (additional)
Ruijuan Xu (additional)
Sahar Saremi (additional)
Qian Li (additional)
Jieun Kim (additional)
Margaret R. McCarter (additional)
Liv R. Dedon (additional)
Tom Angsten (additional)
Nina Balke (additional)
Stephen Jesse (additional)
Mark Asta (additional)
Sergei V. Kalinin (additional)
Lane W. Martin (additional)

References 56 Referenced 94

{'key': 'e_1_2_5_1_1', 'first-page': '321', 'volume-title': 'Piezoelectric Ceramics', 'author': 'Jaffe B.', 'year': '1971'} / Piezoelectric Ceramics by Jaffe B. (1971)
10.1080/01411590500467262
10.1063/1.1599632
10.1080/00150198908007897
10.1063/1.2931706
{'key': 'e_1_2_5_6_1', 'first-page': '014109', 'volume': '80', 'author': 'Cheng C.‐J.', 'year': '2009', 'journal-title': 'Nano Lett.'} / Nano Lett. by Cheng C.‐J. (2009)
10.1002/adfm.200902017
10.1038/srep19630
10.1038/nature03142
10.1038/nature03028
10.1111/j.1551-2916.2009.03061.x
10.1038/nature06459
10.1038/natrevmats.2016.87
10.1088/0953-8984/28/26/263001
10.1557/mrs.2014.1
10.1038/nature02773
10.1126/science.1103218
10.1002/adma.200601098
10.1103/PhysRevLett.108.167601
10.1103/PhysRevB.91.144106
10.1038/nmat4567
10.1126/science.1177046
10.1002/adma.201101164
10.1063/1.1765742
10.1051/jphys:0198600470120205500
10.1103/PhysRevB.64.214103
10.1103/PhysRevB.78.064117
10.1016/S1359-6454(01)00360-3
10.1111/j.1551-2916.2008.02413.x
10.1063/1.3373915
10.1103/PhysRevLett.108.167601
10.1080/00150193.2014.893802
10.1038/ncomms5415
10.1103/PhysRevB.85.024113
10.1103/PhysRevB.94.220101
10.1063/1.2930883
10.1103/PhysRevLett.91.197601
10.1088/0022-3727/44/46/464006
10.1146/annurev-physchem-040513-103609
10.1063/1.1428629
10.1021/nn506753u
10.1038/ncomms9985
10.1002/adfm.201504407
10.1080/00150199308223459
10.1038/nnano.2012.40
10.1038/natrevmats.2016.1
10.1038/nmat3431
10.1021/nl5046796
10.1557/mrs2005.50
10.1021/nn800332g
10.1111/j.1551-2916.2008.02413.x
10.1063/1.1492025
10.1063/1.339293
10.1080/00150190802437746
10.1080/00150198608008205
10.1088/0957-4484/20/7/075401

Dates

Type	When
Created	8 years ago (July 31, 2017, 3:22 a.m.)
Deposited	1 year, 11 months ago (Sept. 7, 2023, 3:42 p.m.)
Indexed	1 day, 22 hours ago (Aug. 28, 2025, 8:55 a.m.)
Issued	8 years ago (July 31, 2017)
Published	8 years ago (July 31, 2017)
Published Online	8 years ago (July 31, 2017)
Published Print	7 years, 10 months ago (Oct. 1, 2017)

Funders 6

Army Research Office 10.13039/100000183
Region: Americas
gov (National government)
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3. U.S. Army Research Laboratory's Army Research Office
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U.S. Department of Energy 10.13039/100000015
Region: Americas
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Awards2
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2. EDCBEE
National Science Foundation 10.13039/100000001
Region: Americas
gov (National government)
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2. NSF
3. US NSF
4. USA NSF
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Region: Americas
gov (National government)
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2. DOE Office of Basic Energy Sciences
3. US Department of Energy's Basic Energy Sciences
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1. DE‐SC0012375
National Science Foundation 10.13039/100000001
Region: Americas
gov (National government)
Labels4
1. U.S. National Science Foundation
2. NSF
3. US NSF
4. USA NSF
Awards1
1. DGE1106400

BibTeX

@article{Damodaran_2017, title={Three‐State Ferroelastic Switching and Large Electromechanical Responses in PbTiO3 Thin Films}, volume={29}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.201702069}, DOI={10.1002/adma.201702069}, number={37}, journal={Advanced Materials}, publisher={Wiley}, author={Damodaran, Anoop R. and Pandya, Shishir and Agar, Josh C. and Cao, Ye and Vasudevan, Rama K. and Xu, Ruijuan and Saremi, Sahar and Li, Qian and Kim, Jieun and McCarter, Margaret R. and Dedon, Liv R. and Angsten, Tom and Balke, Nina and Jesse, Stephen and Asta, Mark and Kalinin, Sergei V. and Martin, Lane W.}, year={2017}, month=jul }

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