Crossref journal-article
Wiley
Advanced Materials (311)
Abstract

The surface‐assisted polymerization and cyclodehydrogenation of specifically designed organic precursors provides a route toward atomically precise graphene nanoribbons, which promises to combine the outstanding electronic properties of graphene with a bandgap that is sufficiently large for room‐temperature digital‐logic applications. Starting from the basic concepts behind the on‐surface synthesis approach, this report covers the progress made in understanding the different reaction steps, in synthesizing atomically precise graphene nanoribbons of various widths and edge structures, and in characterizing their properties, ending with an outlook on the challenges that still lie ahead.

Bibliography

Talirz, L., Ruffieux, P., & Fasel, R. (2016). On‐Surface Synthesis of Atomically Precise Graphene Nanoribbons. Advanced Materials, 28(29), 6222–6231. Portico.

Authors 3
  1. Leopold Talirz (first)
  2. Pascal Ruffieux (additional)
  3. Roman Fasel (additional)
References 85 Referenced 464
  1. 10.1103/RevModPhys.83.851
  2. 10.1126/science.1102896
  3. 10.1073/pnas.1205696109
  4. 10.1038/nnano.2010.89
  5. 10.1109/JPROC.2013.2257633
  6. 10.1002/cphc.201200253
  7. 10.1021/nl0617033
  8. 10.1063/1.2718515
  9. 10.1103/PhysRevLett.102.056403
  10. This problem has recently been addressed by using precursors with long alkyl chains (see ref. 11). In this approach however the GNR edges remain decorated by the flexible alkyl chains which may introduce sources of scattering for charge carriers.
  11. 10.1038/nnano.2007.346
  12. 10.1126/science.1168255
  13. 10.1002/smll.200801943
  14. 10.1038/nchem.891
  15. 10.1038/nature09211
  16. 10.1002/cber.190103402141
  17. 10.1021/ja511995r
  18. 10.1021/nn401948e
  19. {'key': 'e_1_2_6_19_1', 'volume-title': 'Ph.D. Thesis', 'author': 'Söde H.', 'year': '2015'} / Ph.D. Thesis by Söde H. (2015)
  20. 10.1038/ncomms1075
  21. 10.1255/ejms.1162
  22. 10.1038/nchem.1242
  23. 10.1002/anie.201209735
  24. 10.1038/nnano.2014.184
  25. 10.1038/ncomms9098
  26. 10.1021/jacs.5b02523
  27. 10.1143/JPSJ.65.1920
  28. 10.1021/ja400304b
  29. 10.1021/ja107947z
  30. 10.1039/C3NR05710K
  31. 10.1039/c0cc01810d
  32. 10.1021/jp502215m
  33. 10.1039/C4SC01584C
  34. 10.1039/C4CC02757D
  35. 10.1021/jp5106218
  36. 10.1021/acs.accounts.5b00168
  37. 10.1063/1.4858855
  38. 10.1039/C0CP00759E
  39. {'key': 'e_1_2_6_39_1', 'first-page': '12532', 'volume': '9', 'author': 'Simonov K. A.', 'year': '2015', 'journal-title': 'ACS Nano'} / ACS Nano by Simonov K. A. (2015)
  40. 10.1021/acs.accounts.5b00160
  41. 10.1021/ja311099k
  42. 10.1021/nn203129a
  43. 10.1038/ncomms3023
  44. 10.1021/ja510292b
  45. 10.1038/srep00983
  46. 10.1021/acs.nanolett.5b01403
  47. 10.1021/ja909234y
  48. 10.1103/PhysRevLett.97.216803
  49. 10.1103/PhysRevLett.99.186801
  50. 10.1021/nn3021376
  51. 10.1038/nnano.2014.184
  52. 10.1038/ncomms4189
  53. 10.1016/0379-6779(87)90729-6
  54. 10.1103/PhysRevB.54.17954
  55. {'key': 'e_1_2_6_55_1', 'author': 'Ruffieux P.', 'year': '2015', 'journal-title': 'ArXiv 151105037 Cond‐Mat'} / ArXiv 151105037 Cond‐Mat by Ruffieux P. (2015)
  56. {'key': 'e_1_2_6_56_1', 'author': 'Wang S.', 'year': '2015', 'journal-title': 'ArXiv 151104940 Cond‐Mat'} / ArXiv 151104940 Cond‐Mat by Wang S. (2015)
  57. 10.1103/PhysRevLett.110.216804
  58. 10.1103/PhysRevLett.108.216801
  59. 10.1103/PhysRevB.91.045429
  60. 10.1126/science.1156965
  61. 10.1126/science.1103294
  62. 10.1088/0034-4885/68/6/R01
  63. 10.1038/ncomms5253
  64. 10.1103/PhysRevLett.106.187402
  65. 10.1002/9783527632695
  66. 10.1103/PhysRevB.78.195401
  67. 10.1063/1.2713121
  68. 10.1038/nnano.2012.169
  69. 10.1063/1.4855116
  70. 10.1038/498443a
  71. 10.1088/0034-4885/73/5/056501
  72. 10.1002/anie.201303657
  73. 10.1039/C5CC02989A
  74. 10.1021/ja412868w
  75. 10.1002/adma.201305034
  76. 10.1126/science.1244358
  77. 10.1126/science.aac8006
  78. 10.1038/nchem.1819
  79. 10.1039/C5CS00183H
  80. 10.1038/ncomms9006
  81. 10.1038/nature12952
  82. 10.1063/1.4905155
  83. 10.1063/1.4884359
  84. 10.1021/jacs.5b03017
  85. 10.1038/nnano.2014.307
Dates
Type When
Created 9 years, 6 months ago (Feb. 12, 2016, 3:31 a.m.)
Deposited 1 year, 11 months ago (Sept. 11, 2023, 5:24 p.m.)
Indexed 30 minutes ago (Aug. 29, 2025, 5:31 p.m.)
Issued 9 years, 6 months ago (Feb. 12, 2016)
Published 9 years, 6 months ago (Feb. 12, 2016)
Published Online 9 years, 6 months ago (Feb. 12, 2016)
Published Print 9 years ago (Aug. 1, 2016)
Funders 0

None

@article{Talirz_2016, title={On‐Surface Synthesis of Atomically Precise Graphene Nanoribbons}, volume={28}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.201505738}, DOI={10.1002/adma.201505738}, number={29}, journal={Advanced Materials}, publisher={Wiley}, author={Talirz, Leopold and Ruffieux, Pascal and Fasel, Roman}, year={2016}, month=feb, pages={6222–6231} }