DOI: 10.1002/adma.201305095. Ideal Three‐Dimensional Electrode Structures for Electrochemical Energy Storage

Ideal Three‐Dimensional Electrode Structures for Electrochemical Energy Storage

10.1002/adma.201305095

Crossref journal-article

Wiley

Advanced Materials (311)

Abstract

Three‐dimensional electrodes offer great advantages, such as enhanced ion and electron transport, increased material loading per unit substrate area, and improved mechanical stability upon repeated charge–discharge. The origin of these advantages is discussed and the criteria for ideal 3D electrode structure are outlined. One of the common features of ideal 3D electrodes is the use of a 3D carbon‐ or metal‐based porous framework as the structural backbone and current collector. The synthesis methods of these 3D frameworks and their composites with redox‐active materials are summarized, including transition metal oxides and conducting polymers. The structural characteristics and electrochemical performances are also reviewed. Synthesis of composite 3D electrodes is divided into two types — template‐assisted and template‐free methods — depending on whether a pre‐made template is required. The advantages and drawbacks of both strategies are discussed.

Bibliography

Chabi, S., Peng, C., Hu, D., & Zhu, Y. (2013). Ideal ThreeâDimensional Electrode Structures for Electrochemical Energy Storage. Advanced Materials, 26(15), 2440â2445. Portico.

Authors 4

Sakineh Chabi (first)
Chuang Peng (additional)
Di Hu (additional)
Yanqiu Zhu (additional)

References 51 Referenced 232

10.1038/nmat1368
10.1002/adma.200800627
10.1016/j.mser.2011.06.001
10.1002/adma.201102421
10.1002/adma.201202146
10.1557/mrs.2011.156
10.1039/B801151F
10.1021/cr020740l
10.1021/nl304104q
10.1039/C2EE23284G
10.1126/science.1132195
10.1021/ja308676h
10.1021/am401458x
10.1039/c3ee41638k
10.1002/adfm.201203491
10.1016/j.electacta.2013.03.079
10.1016/j.jpowsour.2012.12.072
10.1021/nn4000836
10.1557/jmr.2012.412
10.1002/aenm.201200320
10.1002/adma.201202146
10.1002/adma.201104502
10.1002/cssc.200800087
10.1016/j.carbon.2007.11.042
10.1002/cssc.200900182
10.1126/science.1184126
10.1039/C0EE00404A
10.1002/adfm.200601152
10.1016/j.carbon.2008.09.048
10.1007/978-1-4757-3058-6
10.1038/nmat3001
10.1002/adma.201001029
10.1016/j.nanoen.2012.10.001
10.1038/nnano.2011.38
10.1002/adfm.200700518
10.1021/nl304104q
10.1073/pnas.1210072109
10.1021/nl300528p
10.1002/adma.201104238
10.1002/adfm.200400186
10.1021/nn2033693
10.1002/aenm.201200496
10.1021/nn300097q
10.1016/j.electacta.2007.07.004
10.1039/c2jm34816k
10.1016/j.jpowsour.2011.08.112
10.1016/j.electacta.2012.09.079
10.1039/c2jm15865e
{'key': 'e_1_2_6_49_1', 'first-page': '3797', 'volume': '25', 'author': 'Gong Y.', 'year': '2013', 'journal-title': 'Adv. Mater.'} / Adv. Mater. by Gong Y. (2013)
10.1007/s12274-012-0284-4
10.1002/cssc.201300109

Dates

Type	When
Created	11 years, 8 months ago (Dec. 16, 2013, 4:56 a.m.)
Deposited	1 year, 10 months ago (Oct. 10, 2023, 12:22 p.m.)
Indexed	1 month ago (July 16, 2025, 8:32 a.m.)
Issued	11 years, 8 months ago (Dec. 16, 2013)
Published	11 years, 8 months ago (Dec. 16, 2013)
Published Online	11 years, 8 months ago (Dec. 16, 2013)
Published Print	11 years, 4 months ago (April 1, 2014)

Funders 0

None

BibTeX

@article{Chabi_2013, title={Ideal Three‐Dimensional Electrode Structures for Electrochemical Energy Storage}, volume={26}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.201305095}, DOI={10.1002/adma.201305095}, number={15}, journal={Advanced Materials}, publisher={Wiley}, author={Chabi, Sakineh and Peng, Chuang and Hu, Di and Zhu, Yanqiu}, year={2013}, month=dec, pages={2440–2445} }

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