Abstract
AbstractAdvances in scanning probe microscopies (SPM) have allowed the mechanisms and rates of adsorption, diffusion and reactions on surfaces to be characterized by directly observing the motions of the individual atoms and molecules involved. The importance of oxides as thermal and photocatalysts, chemical sensors, and substrates for epitaxial growth has motivated dynamical SPM studies of oxide surfaces and their formation. Work on the TiO2 (110) surface is reviewed as an example of how dynamic SPM studies have revealed unexpected interactions between adsorbates and defects that influence macroscopic reaction rates. Studies following diffusion, adsorption and phase transitions on bulk and surface oxides are also discussed. A perspective is provided on advanced SPM techniques that hold great promise for yielding new insights into the mechanisms and rates of elemental processes that take place either during oxidation or on oxide surfaces, with particular emphasis on methods that extend the time and chemical resolution of dynamical SPM measurements.
References
116
Referenced
25
10.1017/CBO9780511524356
10.1126/science.280.5370.1732
10.1103/RevModPhys.75.949
10.1103/PhysRevB.42.9206
-
F.Besenbacher F.Jensen E.Laegsgaard K.Mortensen I.Stensgaard Vol.9 USA1991 874.
(
10.1116/1.585486
) 10.1103/PhysRevLett.99.126105
10.1021/jp960861n
10.1063/1.1337068
10.1103/PhysRevLett.76.459
10.1126/science.1099770
10.1063/1.1432113
10.1016/j.susc.2009.07.001
{'key': 'e_1_2_8_13_2', 'volume-title': 'The Surface Science of Metal Oxides', 'author': 'Henrich V. E.', 'year': '1994'}
/ The Surface Science of Metal Oxides by Henrich V. E. (1994)10.1016/S0167-5729(02)00100-0
10.1126/science.1093425
10.1103/PhysRevLett.96.066107
10.1126/science.1159846
10.1038/nmat1592
10.1039/a903106e
10.1016/0927-7757(95)03465-X
10.1103/PhysRevLett.76.791
10.1021/jp0484027
10.1021/jp063619h
10.1021/jp067461c
10.1021/jp809001x
10.1103/PhysRevLett.101.156103
10.1021/jp077677u
10.1016/j.apsusc.2008.01.014
10.1103/PhysRevLett.84.2156
10.1063/1.2814160
10.1016/0009-2614(94)00712-8
10.1021/ja8012825
10.1021/jp020729p
10.1021/jp0523773
10.1016/S0039-6028(99)00720-7
10.1039/b703327n
10.1016/j.susc.2004.05.094
10.1021/jp8077997
10.1016/S0926-860X(01)00557-9
10.1021/jp983555d
10.1016/0040-6090(94)06316-8
10.1016/S0039-6028(03)00986-5
10.1016/j.tsf.2003.10.002
{'key': 'e_1_2_8_44_2', 'author': 'Li M.', 'year': '2004', 'journal-title': 'J. Vac. Sci. and Technol. A'}
/ J. Vac. Sci. and Technol. A by Li M. (2004)10.1016/j.susc.2005.02.007
10.1039/a706191i
10.1006/jssc.1997.7268
10.1107/S0567740878005014
10.1088/0953-8984/11/21/303
10.1103/PhysRevB.52.R14392
10.1016/0039-6028(96)00302-0
10.1016/S0039-6028(97)00818-2
10.1016/S0039-6028(96)00900-4
10.1021/jp003217o
10.1021/jp047383y
10.1021/jp035383c
10.1016/S0021-9517(02)00067-2
10.1016/S0169-4332(03)00938-3
10.1016/0021-9517(84)90371-3
10.1126/science.288.5473.2031
10.1038/nature02863
10.1016/j.cattod.2004.04.033
10.1103/PhysRevLett.79.4222
10.1016/S0039-6028(97)00999-0
10.1126/science.1111568
10.1039/b307879e
10.1016/S0920-5861(03)00377-8
10.1021/jp030142q
10.1103/PhysRevLett.99.056101
10.1088/0957-4484/15/2/011
10.1088/0957-4484/16/3/008
10.1016/S0169-4332(01)00917-5
10.1088/0957-4484/18/4/044024
10.1088/0957-4484/18/4/044025
10.1016/j.susc.2007.08.019
10.1016/j.susc.2008.03.007
10.1016/j.susc.2007.07.027
10.1016/j.susc.2005.07.010
10.1088/0953-8984/20/18/184015
10.1016/j.susc.2006.09.040
10.1016/j.susc.2006.04.040
10.1016/j.susc.2006.04.042
10.1016/j.cattod.2006.06.015
10.1081/CR-120015482
10.1103/PhysRevLett.92.046101
10.1016/S0039-6028(03)00873-2
10.1063/1.459451
10.1007/978-3-642-80281-2_17
10.1016/0039-6028(89)90201-X
10.1016/j.susc.2005.12.020
10.1016/S0039-6028(00)00599-9
10.1016/S0039-6028(02)01104-4
10.1103/PhysRevB.76.045405
10.1103/PhysRevLett.88.246103
10.1021/jp013395x
10.1016/j.susc.2003.10.010
10.1016/S0920-5861(03)00379-1
10.1021/ja00125a013
10.1016/j.susc.2004.01.025
10.1016/S0079-6816(99)00012-X
10.1016/j.tsf.2003.09.016
10.1016/j.tsf.2007.06.070
{'key': 'e_1_2_8_103_2', 'author': 'Bettac A.', 'journal-title': 'J. Vac. Sci. Technol. B'}
/ J. Vac. Sci. Technol. B by Bettac A.10.1021/la803448v
10.1063/1.1144123
10.1021/nn800497y
10.1126/science.279.5358.1907
10.1063/1.2842631
10.1088/0957-4484/20/26/264002
10.1038/nnano.2009.57
10.1126/science.1176210
10.1016/S0926-860X(96)00236-0
10.1103/PhysRevB.75.085439
10.1103/PhysRevLett.92.096101
10.1103/PhysRevLett.100.236101
10.1021/jp060173w
Dates
Type | When |
---|---|
Created | 15 years, 4 months ago (April 8, 2010, 8:23 a.m.) |
Deposited | 2 years ago (Aug. 30, 2023, 1:28 a.m.) |
Indexed | 4 months, 2 weeks ago (April 17, 2025, 3:46 a.m.) |
Issued | 15 years, 1 month ago (July 20, 2010) |
Published | 15 years, 1 month ago (July 20, 2010) |
Published Online | 15 years, 1 month ago (July 21, 2010) |
Published Print | 15 years, 1 month ago (July 20, 2010) |
@article{Altman_2010, title={Mechanisms, Kinetics, and Dynamics of Oxidation and Reactions on Oxide Surfaces Investigated by Scanning Probe Microscopy}, volume={22}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.200903927}, DOI={10.1002/adma.200903927}, number={26–27}, journal={Advanced Materials}, publisher={Wiley}, author={Altman, Eric I. and Schwarz, Udo D.}, year={2010}, month=jul, pages={2854–2869} }