DOI: 10.1002/adma.200802259. Hexyl‐Derivatized Poly(3,4‐ethylenedioxyselenophene): Novel Highly Stable Organic Electrochromic Material with High Contrast Ratio, High Coloration Efficiency, and Low‐Switching Voltage

Hexyl‐Derivatized Poly(3,4‐ethylenedioxyselenophene): Novel Highly Stable Organic Electrochromic Material with High Contrast Ratio, High Coloration Efficiency, and Low‐Switching Voltage

10.1002/adma.200802259

Crossref journal-article

Wiley

Advanced Materials (311)

Bibliography

Li, M., Patra, A., Sheynin, Y., & Bendikov, M. (2009). HexylâDerivatized Poly(3,4âethylenedioxyselenophene): Novel Highly Stable Organic Electrochromic Material with High Contrast Ratio, High Coloration Efficiency, and LowâSwitching Voltage. Advanced Materials, 21(17), 1707â1711. Portico.

Authors 4

Mao Li (first)
Asit Patra (additional)
Yana Sheynin (additional)
Michael Bendikov (additional)

References 48 Referenced 137

10.1002/9783527615377
{'key': 'e_1_2_1_1_3', 'volume-title': 'Handbook of Conducting Polymers. Conjugated Polymers: Theory, Synthesis, Properties, and Characterization', 'author': 'Dyer A. L.', 'year': '2007'} / Handbook of Conducting Polymers. Conjugated Polymers: Theory, Synthesis, Properties, and Characterization by Dyer A. L. (2007)
10.1039/cs9972600147
10.1002/1521-4095(200106)13:11<783::AID-ADMA783>3.0.CO;2-D
10.1002/adma.19900020103
10.1002/adma.200305038
10.1002/adma.200400499
10.1002/adma.200390030
10.1002/adfm.200601145
10.1021/cm021045x
10.1039/b108654e
10.1021/cm0301773
10.1002/adfm.200304317
10.1002/(SICI)1521-4095(200004)12:7<481::AID-ADMA481>3.0.CO;2-C
10.1002/adma.200300376
10.1002/adma.19920040213
10.1002/adma.19970091005
10.1002/1616-3028(20020201)12:2<89::AID-ADFM89>3.0.CO;2-1
10.1021/ma961607w
10.1002/adfm.200304372
10.1021/cm00049a011
10.1002/(SICI)1521-4095(199911)11:16<1379::AID-ADMA1379>3.0.CO;2-Q
10.1021/ma0120409
10.1002/1521-4095(20020517)14:10<717::AID-ADMA717>3.0.CO;2-D
10.1002/1521-3927(20021001)23:15<885::AID-MARC885>3.0.CO;2-X
10.1021/cm020433w
10.1021/cm9706614
10.1039/B613879A
10.1021/cm9801237
10.1021/ma0484173
10.1021/cm020050y
10.1016/0032-3861(94)90332-8
10.1016/0022-0728(94)87085-3
10.1016/0167-2738(94)90403-0
10.1021/ma049222y
10.1002/adfm.200600381
10.1016/0379-6779(94)02492-H
10.1021/ja8018675
The calculated (PBC/B3LYP/6–31G(d)) HOCO and LUCO levels for PEDOS atk = 0 are −3.45 eV and −1.79 eV respectively. For comparison the HOCO and LUCO levels of PEDOT atk = 0 are −3.54 eV and −1.69 eV respectively (ref. 16).
We note that LiBF4in propylene carbonate (PC) was used as a supporting electrolyte and the PEDOS film was obtained using a constant potential mode in PC while in reference [16] LiClO4was used as a supporting electrolyte in acetonitrile and the polymer was obtained by cyclic voltammetry.
Tb% = 82.5 Tc% = 27.6 andQd = 2.25 mC cm−2based on the data in Figure 1.
The CE (in units of cm2C−1) at a specified wavelength is expressed as CE(λ) = ΔOD/Qd ΔOD = log[Tb(λ)/Tc(λ)] whereQdis the injected/ejected charge density (in units of C cm−2) OD is an optical density andTbandTcare the transmittance in the bleached and colored states respectively. For more details see ref. [1a e].
All CE values reported in this paper were measured at 100% of a full switch which corresponds to the highest contrast ratio. We note that even higher CE values can be obtained by narrowing the switching potential window; however the contrast ratio will be compromised. See ref. [8] for details.
All Calculations were performed using the Gaussian 03 program. Gaussian 03 Revision C.02 M. J.Frisch G. W.Trucks H. B.Schlegel G. E.Scuseria M. A.Robb J. R.Cheeseman J. A.MontgomeryJr. T.Vreven K. N.Kudin J. C.Burant J. M.Millam S. S.Iyengar J.Tomasi V.Barone B.Mennucci M.Cossi G.Scalmani N.Rega G. A.Petersson H.Nakatsuji M.Hada M.Ehara K.Toyota R.Fukuda J.Hasegawa M.Ishida T.Nakajima Y.Honda O.Kitao H.Nakai M.Klene X.Li J. E.Knox H. P.Hratchian J. B.Cross V.Bakken C.Adamo J.Jaramillo R.Gomperts R. E.Stratmann O.Yazyev A. J.Austin R.Cammi C.Pomelli J. W.Ochterski P. Y.Ayala K.Morokuma G. A.Voth P.Salvador J. J.Dannenberg V. G.Zakrzewski S.Dapprich A. D.Daniels M. C.Strain O.Farkas D. K.Malick A. D.Rabuck K.Raghavachari J. B.Foresman J. V.Ortiz Q.Cui A. G.Baboul S.Clifford J.Cioslowski B. B.Stefanov G.Liu A.Liashenko P.Piskorz I.Komaromi R. L.Martin D. J.Fox T.Keith M. A.Al‐Laham C. Y.Peng A.Nanayakkara M.Challacombe P. M. W.Gill B.Johnson W.Chen M. W.Wong C.Gonzalez andJ. A.Pople Gaussian Inc. Wallingford CT USA2004. See Supporting Information for details.
The calculated (PBC/B3LYP/6–31G(d)) HOCO and LUCO levels for PEDOS‐C6atk = 0 are −3.30 eV and −1.67 eV respectively. For comparison the HOCO and LUCO levels of PEDOT‐C6atk = 0 are −3.38 eV and −1.55 eV respectively.
Tb% = 90.4 Tc% = 2.23 andQd = 2.08 mC cm−2based on the data in Figure 3a and b.
A coloration efficiency of 686–773 cm2C−1was routinely obtained in several experiments.
10.1016/S1350-4533(96)00034-3

Dates

Type	When
Created	16 years, 6 months ago (Feb. 7, 2009, 2:18 a.m.)
Deposited	1 year, 10 months ago (Sept. 28, 2023, 12:48 p.m.)
Indexed	3 months, 3 weeks ago (April 30, 2025, 8:34 p.m.)
Issued	16 years, 4 months ago (April 22, 2009)
Published	16 years, 4 months ago (April 22, 2009)
Published Online	16 years, 4 months ago (April 22, 2009)
Published Print	16 years, 3 months ago (May 4, 2009)

Funders 0

None

BibTeX

@article{Li_2009, title={Hexyl‐Derivatized Poly(3,4‐ethylenedioxyselenophene): Novel Highly Stable Organic Electrochromic Material with High Contrast Ratio, High Coloration Efficiency, and Low‐Switching Voltage}, volume={21}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.200802259}, DOI={10.1002/adma.200802259}, number={17}, journal={Advanced Materials}, publisher={Wiley}, author={Li, Mao and Patra, Asit and Sheynin, Yana and Bendikov, Michael}, year={2009}, month=apr, pages={1707–1711} }

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