DOI: 10.1002/adma.200701577. Well Ordered Polymer Melts from Blends of Disordered Triblock Copolymer Surfactants and Functional Homopolymers

Well Ordered Polymer Melts from Blends of Disordered Triblock Copolymer Surfactants and Functional Homopolymers

10.1002/adma.200701577

Crossref journal-article

Wiley

Advanced Materials (311)

Bibliography

Tirumala, V. R., Romang, A., Agarwal, S., Lin, E. K., & Watkins, J. J. (2008). Well Ordered Polymer Melts from Blends of Disordered Triblock Copolymer Surfactants and Functional Homopolymers. Advanced Materials, 20(9), 1603â1608. Portico.

Authors 5

Vijay R. Tirumala (first)
Alvin Romang (additional)
Sumit Agarwal (additional)
Eric K. Lin (additional)
James J. Watkins (additional)

References 36 Referenced 75

10.1063/1.882522
10.1007/BFb0017984
10.1021/ma60078a047 / Macromolecules by Liebler L. (1980)
10.1146/annurev.matsci.31.1.323
10.1038/nmat979
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Certain equipment instruments or materials are identified in this paper in order to adequately specify the experimental details. Such identification does not imply recommendation by the National Institute of Standards and Technology nor does it imply the materials are necessarily the best available for the purpose.
10.1016/S1359-0294(96)80118-X
Pluronics Division BASF Corporation private communication.
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10.1016/j.mser.2004.12.003
The scattering profile in absolute intensity units is fit to a Gaussian functional form to determine the full‐width at half‐maximum (FWHM) and intensity of the primary scattering peak. The functional form used is$I_{abs} \!= I_{incoh} \!+ A\!^*\exp \left[ \!{ - \left( {{{q - q_{peak} } \over {2\sigma }}} \right)^2 } \right]$; where$I_{incoh}$is the incoherent scattering intensity A is the intensity prefactor $I_{abs}$ $q_{peak}$and$\sigma$are the reported absolute intensity peak position and FWHM values respectively.
10.1021/ma052323r
X‐ray reflectivity measurements on blend thin films show that (i) the PAA/P123 blends undergo a cylindrical‐to‐lamellae transition between 26.5 to 28.5% PAA by mass and (ii) PAA/P105 blends undergo a lamellae‐to‐cylindrical transition when PAMPS instead of PAA is added at 20% by mass. The observed order‐order transitions are driven more by an increase in the effective interaction parameter χ(homopolymer/EO‐)‐PO than from a simple increase in the effective chain length Nhomopolymer + EO.
10.1021/cm070792x
The uncertainty associated with determining the peak position and full‐width at half‐maximum obtained from the X‐ray and neutron scattering data is smaller than the size of the markers used unless explicitly represented by error bars.

Dates

Type	When
Created	17 years, 4 months ago (April 9, 2008, 4:50 a.m.)
Deposited	1 year, 10 months ago (Oct. 18, 2023, 6:55 a.m.)
Indexed	1 year, 5 months ago (March 20, 2024, 5:10 a.m.)
Issued	17 years, 3 months ago (May 5, 2008)
Published	17 years, 3 months ago (May 5, 2008)
Published Online	17 years, 3 months ago (May 5, 2008)
Published Print	17 years, 3 months ago (May 5, 2008)

Funders 0

None

BibTeX

@article{Tirumala_2008, title={Well Ordered Polymer Melts from Blends of Disordered Triblock Copolymer Surfactants and Functional Homopolymers}, volume={20}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.200701577}, DOI={10.1002/adma.200701577}, number={9}, journal={Advanced Materials}, publisher={Wiley}, author={Tirumala, Vijay R. and Romang, Alvin and Agarwal, Sumit and Lin, Eric K. and Watkins, James J.}, year={2008}, month=may, pages={1603–1608} }

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