Abstract
AbstractIn this review, the recent achievements in the synthesis of inorganic nanomaterials inside the spatially confined volume of individual micro‐ and submicroreactors (emulsions, micelles, organized thin films, polyelectrolyte capsules, etc.) are presented. The advantages and shortcomings of each type of microreactor are discussed. Particular attention is paid to polyelectrolyte capsules as confined microreactors with controlled shell permeability and the possibility of shell engineering on the nanolevel, thus tailoring different functionalities. Nanomaterials synthesized inside a confined multifunctional microreactor have several advantages: i) absence of particle aggregates, ii) amorphous or metastable crystal phases, and iii) unique composite inorganic/inorganic and inorganic/organic structures.
References
164
Referenced
337
10.1021/cr010350j
- Chem. Mater.2001 13(special issue on Nanostructured and Functional Materials).
- MRS Bull.2001 26(special issue on Hybrid Materials).
10.1021/cr00024a006
10.1016/S0022-0728(97)00458-0
10.1002/1521-3773(20010817)40:16<3001::AID-ANIE3001>3.0.CO;2-5
10.1021/cr970102g
10.1063/1.1429749
10.1007/s003399900169
10.1021/cr980002q
10.1021/ma011797x
10.1021/ma0117357
10.1021/cm980468p
10.1016/S1359-0286(00)00015-2
10.1021/cm021238k
10.1021/jp026929i
10.1021/la980696y
10.1002/adma.19950071117
10.1021/cr0200062
10.1071/CH01033
10.1016/S0167-2991(01)81275-1
10.1126/science.261.5126.1286
10.1002/(SICI)1521-4095(199802)10:3<195::AID-ADMA195>3.0.CO;2-V
10.1007/3-540-36408-0_4
10.1039/b302404k
10.1021/cm00054a017
10.1038/420020a
10.1039/b008534k
10.1002/1521-3773(20000901)39:17<3137::AID-ANIE3137>3.0.CO;2-D
10.1021/cr00036a003
10.1021/ma991782n
- E. D. Sudol M. S. El‐Aasser inEmulsion Polymerization and Emulsion Polymers(Eds: P. A. Lovell M. S. El‐Aasser) John Wiley and Sons Chichester UK1997 p. 699.
10.1021/ma990299
10.1006/jcis.2001.7792
10.1016/S0021-9797(03)00276-5
10.1006/jcis.2001.7635
10.1021/la9705266
10.1021/cm9601345
10.1246/cl.2002.62
10.1002/1521-4095(200104)13:7<500::AID-ADMA500>3.0.CO;2-3
10.1002/(SICI)1521-4079(199810)33:7/8<1155::AID-CRAT1155>3.0.CO;2-A
10.1039/b206020e
10.1016/S0927-7757(03)00237-1
10.1016/S0022-3093(05)80588-5
10.1016/0166-6622(92)80221-M
10.1023/A:1017920823963
10.1021/jp025715y
10.1016/S0965-9773(97)90063-5
{'key': 'e_1_2_1_50_2', 'first-page': '89', 'volume': '9', 'author': 'Lee M. S.', 'year': '2003', 'journal-title': 'J. Ind. Eng. Chem.'}
/ J. Ind. Eng. Chem. by Lee M. S. (2003)10.1023/A:1020706106450
10.1039/b002720k
10.1107/S0021889899012777
10.1021/cm011121g
10.1006/jcis.2001.7579
10.1111/j.1151-2916.2002.tb00433.x
10.1021/la00054a004
10.1016/S0926-3373(00)00265-4
10.1021/la9705266
10.1002/adfm.200290006
10.1021/cm970113q
10.1021/jp0262057
10.1016/0040-6031(89)87204-1
10.1016/S1385-8947(99)00037-6
10.1080/10242420290025539
10.1016/S0141-0229(00)00268-4
10.1016/S0927-7757(96)03915-5
10.1021/cr00041a001
10.1039/b104483b
10.1351/pac199365122573
10.1016/S0927-7757(96)03788-0
10.1039/b004916f
10.1021/la9909291
10.1021/cm00020a021
10.1016/S0920-5861(00)00250-9
10.1016/S1350-4177(02)00086-X
10.1002/1616-3028(200104)11:2<136::AID-ADFM136>3.0.CO;2-3
10.1002/bbpc.19971011119
10.1021/jp021223
10.1016/S1387-7003(02)00523-3
10.1021/jp952668j
10.1039/B203203C
10.1016/S0167-2991(01)81532-9
10.1016/S0920-5861(00)00606-4
10.1016/S0927-6513(97)00028-X
10.1021/jp0218645
10.1016/S0926-860X(97)00074-4
10.1023/A:1015912608285
10.1016/S0926-860X(97)00074-4
10.1021/ja9714604
10.1021/cm960469m
10.1016/S0168-3659(01)00264-4
{'key': 'e_1_2_1_93_2', 'first-page': '312', 'volume': '92', 'author': 'Luis G. P.', 'year': '1996', 'journal-title': 'Anal. Quim.'}
/ Anal. Quim. by Luis G. P. (1996)10.1016/S1359-0294(03)00016-5
10.1006/jcis.1997.5031
10.1021/la000788z
10.1021/la0206357
10.1038/39287
10.1038/30211
10.1002/1521-3773(20010119)40:2<442::AID-ANIE442>3.0.CO;2-2
- P. M. Harrison P. J. Artymuik G. C. Ford D. M. Lawson J. M. A. Smith A. Treffry J. L. White inBiomineralization: Chemical and Biochemical Perspectives(Eds: S. Mann J. Webb R. J. P. Williams) VCH Weinheim1989 p. 257.
10.1021/la001306m
10.1016/0040-6090(92)90417-A
10.1126/science.277.5330.1232
10.1021/ma981927a
10.1021/cm021045x
10.1021/la960959t
10.1021/ma991645q
10.1021/la001298
10.1021/la0112099
10.1021/cm020945a
10.1021/la015725a
10.1021/la025731m
10.1021/la010755z
10.1021/cm990804h
10.1021/cm020934h
10.1021/la980587j
10.1021/la991089t
10.1016/S0040-6090(98)00697-X
10.1016/S0927-7757(01)00976-1
10.1016/S0040-6090(95)08472-X
10.1016/S0927-7757(01)00961-X
10.1021/la000069k
10.1016/S0927-7765(01)00264-8
10.1002/(SICI)1099-1581(1998100)9:10/11<759::AID-PAT846>3.0.CO;2-Q
10.1002/(SICI)1521-3773(19980904)37:16<2201::AID-ANIE2201>3.0.CO;2-E
10.1002/1521-3927(20010101)22:1<44::AID-MARC44>3.0.CO;2-U
10.1002/1521-4095(200109)13:17<1324::AID-ADMA1324>3.0.CO;2-L
10.1021/la026101n
10.1021/nl0100015
10.1016/S0927-7757(01)01104-9
10.1016/S0378-5173(02)00161-8
10.1021/la036177z
10.1021/ja002911e
- G.B Sukhorukov inNovel Methods to Study Interfacial Layers(Eds: D. Mobius R Miller) Elsevier Science Amsterdam2001 p. 384.
- L. Dahne C. Peyratout Angew. Chem. Int. Ed.2004 in press.
10.1039/a809106d
10.1021/cr000700m
10.1021/cr970025p
10.1021/jp990095v
10.1006/jcis.2001.8102
10.1002/(SICI)1521-4095(200001)12:2<112::AID-ADMA112>3.0.CO;2-P
- R. Ghan T. Shutava A. Patel V. John Y. Lvov Macromolecules2004 in press.
- I. L. Radtchenko Ph.D. Thesis Potsdam University Potsdam Germany2003.
10.1063/1.1566732
10.1021/cr960398a
10.1002/marc.200390069
10.1021/la0256228
10.1016/S0167-577X(02)01061-3
10.1021/jp026929i
10.1021/cm0211251
10.1021/la0268707
10.1080/01496399508013149
10.1177/026361749801601004
10.1021/cm0341585
10.1002/cphc.200300740
10.1021/la020052x
10.1039/b306197c
10.1016/S0378-5173(02)00140-0
10.1002/marc.200390041
10.1021/la970765t
10.1002/(SICI)1521-3935(19980201)199:2<247::AID-MACP247>3.0.CO;2-9
10.1021/jp026007f
10.1021/cm011300y
10.1002/anie.200352068
Dates
Type | When |
---|---|
Created | 21 years, 4 months ago (April 26, 2004, 11:01 a.m.) |
Deposited | 1 year, 9 months ago (Nov. 20, 2023, 2:15 p.m.) |
Indexed | 3 weeks, 2 days ago (Aug. 3, 2025, 12:16 a.m.) |
Issued | 21 years, 4 months ago (April 19, 2004) |
Published | 21 years, 4 months ago (April 19, 2004) |
Published Online | 21 years, 4 months ago (April 26, 2004) |
Published Print | 21 years, 4 months ago (April 19, 2004) |
@article{Shchukin_2004, title={Nanoparticle Synthesis in Engineered Organic Nanoscale Reactors}, volume={16}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.200306466}, DOI={10.1002/adma.200306466}, number={8}, journal={Advanced Materials}, publisher={Wiley}, author={Shchukin, D. G. and Sukhorukov, G. B.}, year={2004}, month=apr, pages={671–682} }