DOI: 10.1002/adma.19960080806. Ultrathin graphite oxide–polyelectrolyte composites prepared by self‐assembly: Transition between conductive and non‐conductive states

Ultrathin graphite oxide–polyelectrolyte composites prepared by self‐assembly: Transition between conductive and non‐conductive states

10.1002/adma.19960080806

Crossref journal-article

Wiley

Advanced Materials (311)

Abstract

Ultrathin films of graphite–polymer composites, which are required for sensors applications, are the target of the work reported here. The preparation and characterization of ultrathin films composed of self‐assembled graphite oxide (GO) platelets and polyelectrolytes are described, followed by the in situ reduction of GO to a conductive graphite‐like state (G) by chemical and electrochemical methods. Particular attention is paid to the non‐conductive to conductive transition that occurs on reduction and the behavior of incorporated CdS particles.

Bibliography

Kotov, N. A., DÃ©kÃ¡ny, I., & Fendler, J. H. (1996). Ultrathin graphite oxideâpolyelectrolyte composites prepared by selfâassembly: Transition between conductive and nonâconductive states. Advanced Materials, 8(8), 637â641. Portico.

Authors 3

Nicholas A. Kotov (first)
Imre Dékány (additional)
Janos H. Fendler (additional)

References 52 Referenced 576

{'key': 'e_1_2_1_1_2', 'volume-title': 'Lithium Batteries, New Materials and New Perspectives', 'author': 'Dahn J. R.', 'year': '1993'} / Lithium Batteries, New Materials and New Perspectives by Dahn J. R. (1993)
10.1088/0964-1726/3/4/004
10.1126/science.1962191
{'key': 'e_1_2_1_4_2', 'first-page': '1480', 'volume': '95', 'author': 'Decher G.', 'year': '1991', 'journal-title': 'Ber. Bunsenges. Phys. Chem.'} / Ber. Bunsenges. Phys. Chem. by Decher G. (1991)
10.1016/0040-6090(92)90417-A
10.1016/0040-6090(94)90616-5
10.1021/ja00127a026
10.1021/ma00077a052
10.1021/ja00098a055
10.1126/science.265.5170.370
10.1021/ja00090a059
10.1002/anie.199501551
{'key': 'e_1_2_1_8_2', 'volume-title': 'Comprehensive Supramolecular Chemistry', 'author': 'Mallouk T. E.', 'year': '1996'} / Comprehensive Supramolecular Chemistry by Mallouk T. E. (1996)
{'key': 'e_1_2_1_8_3', 'volume-title': 'Two‐ and Three‐dimensional Inorganic Networks, Part I–Layered Solids and their Intercalaction Chemistry', 'author': 'Decher G.', 'year': '1996'} / Two‐ and Three‐dimensional Inorganic Networks, Part I–Layered Solids and their Intercalaction Chemistry by Decher G. (1996)
{'key': 'e_1_2_1_9_2', 'first-page': '793', 'volume': '31', 'author': 'Rikukawa M.', 'year': '1994', 'journal-title': 'J. Macromol. Sci.'} / J. Macromol. Sci. by Rikukawa M. (1994)
10.1016/0379-6779(93)91195-8
10.1557/S0883769400036927 / MRS Bull. by Whitten D. G. (1995)
10.1038/374771a0
10.1016/0920-2307(93)90004-X
10.1063/1.352780
10.1016/0038-1098(94)90512-6
10.1016/0379-6779(94)90030-2
{'key': 'e_1_2_1_11_5', 'first-page': '1062', 'volume': '29', 'author': 'Vovchemko L. L.', 'year': '1993', 'journal-title': 'Inorg. Mater. (Engl. Transl. )'} / Inorg. Mater. (Engl. Transl. ) by Vovchemko L. L. (1993)
10.1016/0379-6779(93)90751-H
10.1002/actp.1992.010430304
10.1016/0749-6036(92)90207-L
10.1016/0039-6028(91)90110-E
10.1016/0379-6779(91)91526-G
{'key': 'e_1_2_1_11_11', 'first-page': '903', 'volume': '32', 'author': 'Chuiko A. A.', 'year': '1990', 'journal-title': 'Vysokomol. Soedin., Ser. B'} / Vysokomol. Soedin., Ser. B by Chuiko A. A. (1990)
10.1021/la00022a069
10.1039/c39920001326
10.1021/ma00051a037
10.1126/science.258.5081.441
10.1016/0266-3538(93)90133-2
10.1016/0010-4361(93)90041-6
10.1016/0032-3861(94)90028-0
10.1002/pen.760320908
10.1016/0043-1648(92)90146-Y
10.1002/pen.760311803
10.1002/app.1993.070470805
{'key': 'e_1_2_1_15_2', 'volume-title': 'Advances in Polymer Science', 'author': 'Fendler J. H.', 'year': '1994'} / Advances in Polymer Science by Fendler J. H. (1994)
10.1021/j150500a001
10.1021/j100035a005
10.1016/0008-6223(94)90168-6
N. A.Kotov T.Haraszti L.Turi I.Dékány J. H.Fendler Presentation at the NATO Advanced Research Workshop on “Nanoparticles in Solids and Solutions–An Integrated Approach to their Preparation and Characterization” Szeged Hungary March 8–13 1996.
10.1021/la00048a052
{'key': 'e_1_2_1_20_3', 'first-page': '79', 'volume': '6', 'author': 'Carrara S.', 'year': '1995', 'journal-title': 'J. Mater. Sci.'} / J. Mater. Sci. by Carrara S. (1995)
10.1016/0379-6779(94)02423-V
10.1016/0038-1098(94)90005-1
10.1002/cber.18980310237
10.1002/jlac.18601140103
{'key': 'e_1_2_1_21_4', 'first-page': '118', 'volume': '691', 'author': 'Boehm H. P.', 'year': '1996', 'journal-title': 'Liebigs Ann. Chem.'} / Liebigs Ann. Chem. by Boehm H. P. (1996)

Dates

Type	When
Created	20 years, 7 months ago (Dec. 30, 2004, 2:53 p.m.)
Deposited	1 year, 10 months ago (Oct. 18, 2023, 8:17 p.m.)
Indexed	2 weeks, 6 days ago (Aug. 2, 2025, 1:22 a.m.)
Issued	29 years ago (Aug. 1, 1996)
Published	29 years ago (Aug. 1, 1996)
Published Online	20 years, 9 months ago (Oct. 29, 2004)
Published Print	29 years ago (Aug. 1, 1996)

Funders 0

None

BibTeX

@article{Kotov_1996, title={Ultrathin graphite oxide–polyelectrolyte composites prepared by self‐assembly: Transition between conductive and non‐conductive states}, volume={8}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.19960080806}, DOI={10.1002/adma.19960080806}, number={8}, journal={Advanced Materials}, publisher={Wiley}, author={Kotov, Nicholas A. and Dékány, Imre and Fendler, Janos H.}, year={1996}, month=aug, pages={637–641} }

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