DOI: 10.1002/adma.19950070210. New polymer electrolyte nanocomposites: Melt intercalation of poly(ethylene oxide) in mica‐type silicates

New polymer electrolyte nanocomposites: Melt intercalation of poly(ethylene oxide) in mica‐type silicates

10.1002/adma.19950070210

Crossref journal-article

Wiley

Advanced Materials (311)

Abstract

The electrochemical performance of polymer‐based batteries can be improved by the addition of inorganic fillers to the polymer electrolyte, giving composite polymer electrolytes. The use of polymer nanocomposites, where the dimensions of the filler particles are reduced, should lead to the improvement of the performance of the electrolytes. Here, the direct intercalation of poly(ethylene oxide) into Na⊕ and Li⊕‐exchanged layered silicates and the properties of the resulting nanocomposites is reported.

Bibliography

Vaia, R. A., Vasudevan, S., Krawiec, W., Scanlon, L. G., & Giannelis, E. P. (1995). New polymer electrolyte nanocomposites: Melt intercalation of poly(ethylene oxide) in micaâtype silicates. Advanced Materials, 7(2), 154â156. Portico.

Authors 5

Richard A. Vaia (first)
S. Vasudevan (additional)
Wlodzimierz Krawiec (additional)
Lawrence G. Scanlon (additional)
Emmanual P. Giannelis (additional)

References 26 Referenced 584

{'key': 'e_1_2_1_1_2', 'first-page': '375', 'volume': '28', 'author': 'Skaarup S.', 'year': '1980', 'journal-title': 'B. Solid State Ionics'} / B. Solid State Ionics by Skaarup S. (1980)
M.Nookola L. G.Scanlon R. A.Marsh B.Kumar A. K.Sircar J. Appl. Electrochem. in press.
10.1016/0921-5107(92)90041-7
10.1149/1.2085900
10.1016/0038-1098(91)90876-W
V.Mehrotra E. P.Giannclis in Polymer Based Molecular Composites (Eds: D. W. Shaefer J. E. Mark) Mater. Res. Soc. Proc. Pittsburgh PA1990 171.
E. P.Giannelis V.Mehrotra M. W.Russell in Better Ceramics Through Chemistry (Eds: C. J. Brinker D. E. Clark D. R. Ulrich B. J. J. Zelinski) Mater. Res. Soc. Proc. Pittsburgh PA 1990.
10.1016/0167-2738(92)90353-Q
E. P.Giannelis V.Mehrotra O.Tse R. A.Vaia T.‐C.Sung inSynthesis and Processing of Ceramics: Scientific Issues(Eds: W. E. Rhine T. M. Shaw R. J. Gottshall Y. Chen ) Mater. Res. Soc. Proc. Pittsburgh PA 1992.
10.1007/BF03222789
10.1016/0167-2738(89)90272-5
10.1021/ja00193a078
10.1016/0022-4596(91)90221-3
10.1021/cm00017a006
10.1557/JMR.1991.1103
10.1021/ja00041a048
10.1557/JMR.1992.2599
10.1002/adma.19900021108
10.1021/cm00024a048
10.1002/actp.1994.010450201
10.1021/cm00030a019
10.1021/cm00036a004
We have found that the extent of mixing significantly affects the reaction kinetics.
10.1002/adma.19900020603
WKrawiec L. G.Scanlon J. P.Fellner R. A.Vaia S.Vasudevan E. P.Giannelis J. Power Sources in press.
The O/Li ratio for the nanocomposite represents an effective ratio calculated from the cation exchange capacity of montmorillonite (80 meq/ 100 g) and the maximum amount of intercalated PEO (27 wt.%).

Dates

Type	When
Created	20 years, 3 months ago (May 29, 2005, 3:44 a.m.)
Deposited	1 year, 9 months ago (Nov. 20, 2023, 7:29 p.m.)
Indexed	1 week ago (Aug. 23, 2025, 1:01 a.m.)
Issued	30 years, 6 months ago (Feb. 1, 1995)
Published	30 years, 6 months ago (Feb. 1, 1995)
Published Online	20 years, 11 months ago (Sept. 15, 2004)
Published Print	30 years, 6 months ago (Feb. 1, 1995)

Funders 0

None

BibTeX

@article{Vaia_1995, title={New polymer electrolyte nanocomposites: Melt intercalation of poly(ethylene oxide) in mica‐type silicates}, volume={7}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.19950070210}, DOI={10.1002/adma.19950070210}, number={2}, journal={Advanced Materials}, publisher={Wiley}, author={Vaia, Richard A. and Vasudevan, S. and Krawiec, Wlodzimierz and Scanlon, Lawrence G. and Giannelis, Emmanual P.}, year={1995}, month=feb, pages={154–156} }

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