DOI: 10.1002/adma.19920040715. Poly(glucose‐pyrrole) modified electrodes: A novel chiral electrode for enantioselective recognition

Poly(glucose‐pyrrole) modified electrodes: A novel chiral electrode for enantioselective recognition

10.1002/adma.19920040715

Crossref journal-article

Wiley

Advanced Materials (311)

Abstract

Chiral electrode materials possessing enantioselective recognition properties or capable of performing chiral electrosynthesis are of great potential interest. The synthesis of a chiral pyrrolic monomer (see figure) and the enantioselective properties of the modified electrode surface obtained upon its polymerization are reported. magnified image

Bibliography

Moutet, J., SaintlâAman, E., TranâVan, F., Angibeaud, P., & Utille, J. (1992). Poly(glucoseâpyrrole) modified electrodes: A novel chiral electrode for enantioselective recognition. Advanced Materials, 4(7â8), 511â513. Portico.

Authors 5

Jean‐Claude Moutet (first)
Eric Saintl‐Aman (additional)
François Tran‐Van (additional)
Pierre Angibeaud (additional)
Jean‐Pierre Utille (additional)

References 18 Referenced 81

A.Yamagishi A.Aramata J. Chem. Soc. Chem. Commun.1984 452. (10.1039/c39840000452)
(a)M.Lemaire D.Delabouglise R.Garreau A.Guy J.Roncali J. Chem. Soc. Chem. Commun.1988 658; (10.1039/c39880000658)
10.1002/masy.19880200159
D.Kotkar V.Joshi P. K.Ghosh J. Chem. Soc. Chem. Common.1988 917. (10.1039/c39880000917)
10.1021/ja00845a061
10.1021/ja00321a028
10.1002/adma.19890010404
10.1149/1.2114249
10.1002/adma.19910030406
{'key': 'e_1_2_1_9_2', 'first-page': '434', 'volume-title': 'Organic Synthesis', 'author': 'Reynolds D. W.', 'year': '1955'} / Organic Synthesis by Reynolds D. W. (1955)
G. R.Clemo G. R.Ramage J. Chem. Soc.1931 49.
10.1021/ja00966a052
10.1016/0022-0728(89)80205-0
1H−NMR (CDCl3) δ(ppm): 2.05 (m 12H CH3CO) 2.79 (t J=7 Hz 2 H H‐8) 3.80 (m 114 H‐5) 4.22 (m 4 H H‐6 H‐7) 5.14 (m 3 H H‐2 H‐3 H‐4) 5.65 (d J =8 Hz 1H H‐1) 6.10 (t J = 2 Hz 2 H H‐ß ß) 6.64 (t J = 2 Hz 2H H‐β β).13C−NMR (CDCL3) δ(ppm): 20.52‐20.76 (CH3CO) 36.17 (C‐7) 44.56 (C‐8) 61.68 (C‐6) 67.62 (C‐4) 70.10 (C‐2) 72.64 (C‐3 and C‐5) 91.64 (C‐1) 108.39 (C‐β) 120.51 (C‐β) 169.18‐170.55 (CH3CO) (see ref. [16] for13C−NMR data of glucopyranose derivatives). Mass spectroscopy (D‐CI): calcd. 469; found 470 (m + H⊕) 487 (m + NH). UV/Vis spectroscopy (C2H5OH) λmax[nm] (log(ε/ M−1cm−1)): 229 (3.5) 290 (3.2). UV/VIS spectroscopy for the film on the ITO electrode: 350 nm (sh). [α](c =1. CHCl3) = + 10° for 1; [α](c =1 CHCl3) − +7° for 2.
10.1021/ar00163a004
10.1016/0022-0728(90)87116-2
10.1002/bbpc.19870910927 / Ber. Bunsenges. Phys. Chem. by Beck F. (1987)
{'key': 'e_1_2_1_16_2', 'first-page': '49', 'volume': '41', 'author': 'Bock K.', 'year': '1983', 'journal-title': 'Adv. Carbohydr. Chem. Biochem.'} / Adv. Carbohydr. Chem. Biochem. by Bock K. (1983)

Dates

Type	When
Created	20 years, 3 months ago (May 29, 2005, 3:26 a.m.)
Deposited	2 years ago (Sept. 1, 2023, 12:29 p.m.)
Indexed	2 weeks ago (Aug. 20, 2025, 8:49 a.m.)
Issued	33 years, 2 months ago (July 1, 1992)
Published	33 years, 2 months ago (July 1, 1992)
Published Online	20 years, 10 months ago (Oct. 29, 2004)
Published Print	33 years, 2 months ago (July 1, 1992)

Funders 0

None

BibTeX

@article{Moutet_1992, title={Poly(glucose‐pyrrole) modified electrodes: A novel chiral electrode for enantioselective recognition}, volume={4}, ISSN={1521-4095}, url={http://dx.doi.org/10.1002/adma.19920040715}, DOI={10.1002/adma.19920040715}, number={7–8}, journal={Advanced Materials}, publisher={Wiley}, author={Moutet, Jean‐Claude and Saintl‐Aman, Eric and Tran‐Van, François and Angibeaud, Pierre and Utille, Jean‐Pierre}, year={1992}, month=jul, pages={511–513} }

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