DOI: 10.1002/adfm.201302169. Carbon‐Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability

Carbon‐Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability

10.1002/adfm.201302169

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

The lithium sulfur battery system has been studied since the late 1970s and has seen renewed interest in recent years. However, even after three decades of intensive research, prolonged cycling can only be achieved when a large excess of electrolyte and lithium is used. Here, for the first time, a balanced and stable lithium sulfur full cell is demonstrated with silicon–carbon as well as all‐carbon anodes. More than 1000 cycles, a specific capacity up to 1470 mAh g−1 sulfur (720 mAh g−1 cathode), and a high coulombic efficiency of over 99% even with a low amount of electrolyte are achieved. The alternative anodes do not suffer from electrolyte depletion, which is found to be the main cause of cell failure when using metallic lithium anodes.

Bibliography

BrÃ¼ckner, J., Thieme, S., BÃ¶ttgerâHiller, F., Bauer, I., Grossmann, H. T., Strubel, P., Althues, H., Spange, S., & Kaskel, S. (2013). CarbonâBased Anodes for Lithium Sulfur Full Cells with High Cycle Stability. Advanced Functional Materials, 24(9), 1284â1289. Portico.

Authors 9

Jan Brückner (first)
Sören Thieme (additional)
Falko Böttger‐Hiller (additional)
Ingolf Bauer (additional)
Hannah Tamara Grossmann (additional)
Patrick Strubel (additional)
Holger Althues (additional)
Stefan Spange (additional)
Stefan Kaskel (additional)

References 36 Referenced 175

10.1038/nmat2460
10.1002/anie.201100637
10.1039/c002639e
10.1038/ncomms2327
10.1039/c2cc17925c
{'key': 'e_1_2_6_6_1', 'author': 'Thieme S.', 'year': '2013', 'journal-title': 'J. Mater. Chem. A'} / J. Mater. Chem. A by Thieme S. (2013)
10.1039/c3cc42841a
10.1039/c2ee03495f
10.1126/science.1223985
10.1021/nl400543y
10.1073/pnas.1220992110
10.1039/c3ee00072a
10.1149/1.3148721
Y. V.Mikhaylik US 7 354 680 B2 2008. (10.1016/j.jnoncrysol.2007.08.087)
10.1016/j.electacta.2006.08.016
10.3390/en5125190
10.1016/j.electacta.2012.03.081
10.1002/anie.201107817
10.1038/nmat2460
10.1039/c1ee01219c
10.1002/anie.200907324
10.1021/nl100504q
10.1016/j.elecom.2011.10.020
10.1021/nn303393p
10.1149/1.2160429
10.1021/la300306v
10.1149/1.2054777
10.1016/S0008-6223(00)00237-2
10.1002/anie.201209849
10.1039/c2cc35112a
10.1016/S0378-7753(98)00128-1
10.1016/j.electacta.2012.07.118
10.1149/1.1806394
10.1149/1.1838585
10.1002/ange.200504327
10.1002/anie.200504327

Dates

Type	When
Created	11 years, 11 months ago (Aug. 27, 2013, 3:04 a.m.)
Deposited	1 year, 9 months ago (Oct. 27, 2023, 5:58 p.m.)
Indexed	1 week, 4 days ago (Aug. 12, 2025, 5:49 p.m.)
Issued	11 years, 11 months ago (Aug. 27, 2013)
Published	11 years, 11 months ago (Aug. 27, 2013)
Published Online	11 years, 11 months ago (Aug. 27, 2013)
Published Print	11 years, 5 months ago (March 1, 2014)

Funders 0

None

BibTeX

@article{Br_ckner_2013, title={Carbon‐Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability}, volume={24}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.201302169}, DOI={10.1002/adfm.201302169}, number={9}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Brückner, Jan and Thieme, Sören and Böttger‐Hiller, Falko and Bauer, Ingolf and Grossmann, Hannah Tamara and Strubel, Patrick and Althues, Holger and Spange, Stefan and Kaskel, Stefan}, year={2013}, month=aug, pages={1284–1289} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2025,
        8,
        12
      ]
    ],
    "date-time": "2025-08-12T21:49:13Z",
    "timestamp": 1755035353467
  },
  "reference-count": 36,
  "publisher": "Wiley",
  "issue": "9",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2013,
            8,
            27
          ]
        ],
        "date-time": "2013-08-27T00:00:00Z",
        "timestamp": 1377561600000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2014,
        3
      ]
    ]
  },
  "abstract": "<jats:p>The lithium sulfur battery system has been studied since the late 1970s and has seen renewed interest in recent years. However, even after three decades of intensive research, prolonged cycling can only be achieved when a large excess of electrolyte and lithium is used. Here, for the first time, a balanced and stable lithium sulfur full\u00a0cell is demonstrated with silicon\u2013carbon as well as all\u2010carbon anodes. More than 1000 cycles, a specific capacity up to 1470 mAh g<jats:sup>\u22121</jats:sup>\n<jats:sub>sulfur</jats:sub> (720 mAh g<jats:sup>\u22121</jats:sup>\n<jats:sub>cathode</jats:sub>), and a high coulombic efficiency of over 99% even with a low amount of electrolyte are achieved. The alternative anodes do not suffer from electrolyte depletion, which is found to be the main cause of cell failure when using metallic lithium anodes.</jats:p>",
  "DOI": "10.1002/adfm.201302169",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2013,
        8,
        27
      ]
    ],
    "date-time": "2013-08-27T07:04:48Z",
    "timestamp": 1377587088000
  },
  "page": "1284-1289",
  "source": "Crossref",
  "is-referenced-by-count": 175,
  "title": "Carbon\u2010Based Anodes for Lithium Sulfur Full Cells with High Cycle Stability",
  "prefix": "10.1002",
  "volume": "24",
  "author": [
    {
      "given": "Jan",
      "family": "Br\u00fcckner",
      "sequence": "first",
      "affiliation": [
        {
          "name": "Fraunhofer Institute for Material and Beam Technology (IWS)  Winterbergstra\u00dfe 28 01277 Dresden Germany"
        }
      ]
    },
    {
      "given": "S\u00f6ren",
      "family": "Thieme",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Fraunhofer Institute for Material and Beam Technology (IWS)  Winterbergstra\u00dfe 28 01277 Dresden Germany"
        }
      ]
    },
    {
      "given": "Falko",
      "family": "B\u00f6ttger\u2010Hiller",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Chair Polymer Chemistry Chemnitz University of Technology  Stra\u00dfe der Nationen 62 09111 Chemnitz Germany"
        }
      ]
    },
    {
      "given": "Ingolf",
      "family": "Bauer",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Fraunhofer Institute for Material and Beam Technology (IWS)  Winterbergstra\u00dfe 28 01277 Dresden Germany"
        }
      ]
    },
    {
      "given": "Hannah Tamara",
      "family": "Grossmann",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Fraunhofer Institute for Material and Beam Technology (IWS)  Winterbergstra\u00dfe 28 01277 Dresden Germany"
        }
      ]
    },
    {
      "given": "Patrick",
      "family": "Strubel",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Fraunhofer Institute for Material and Beam Technology (IWS)  Winterbergstra\u00dfe 28 01277 Dresden Germany"
        }
      ]
    },
    {
      "given": "Holger",
      "family": "Althues",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Fraunhofer Institute for Material and Beam Technology (IWS)  Winterbergstra\u00dfe 28 01277 Dresden Germany"
        }
      ]
    },
    {
      "given": "Stefan",
      "family": "Spange",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Chair Polymer Chemistry Chemnitz University of Technology  Stra\u00dfe der Nationen 62 09111 Chemnitz Germany"
        }
      ]
    },
    {
      "given": "Stefan",
      "family": "Kaskel",
      "sequence": "additional",
      "affiliation": [
        {
          "name": "Fraunhofer Institute for Material and Beam Technology (IWS)  Winterbergstra\u00dfe 28 01277 Dresden Germany"
        },
        {
          "name": "Chair Inorganic Chemistry I Dresden University of Technology  Bergstra\u00dfe 66 D\u201001062 Dresden Germany"
        }
      ]
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2013,
        8,
        27
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_6_1_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nmat2460"
    },
    {
      "key": "e_1_2_6_2_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201100637"
    },
    {
      "key": "e_1_2_6_3_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c002639e"
    },
    {
      "key": "e_1_2_6_4_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/ncomms2327"
    },
    {
      "key": "e_1_2_6_5_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c2cc17925c"
    },
    {
      "key": "e_1_2_6_6_1",
      "author": "Thieme S.",
      "year": "2013",
      "journal-title": "J. Mater. Chem. A"
    },
    {
      "key": "e_1_2_6_7_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c3cc42841a"
    },
    {
      "key": "e_1_2_6_8_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c2ee03495f"
    },
    {
      "key": "e_1_2_6_9_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.1223985"
    },
    {
      "key": "e_1_2_6_10_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nl400543y"
    },
    {
      "key": "e_1_2_6_11_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1073/pnas.1220992110"
    },
    {
      "key": "e_1_2_6_12_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c3ee00072a"
    },
    {
      "key": "e_1_2_6_13_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.3148721"
    },
    {
      "key": "e_1_2_6_14_1",
      "doi-asserted-by": "crossref",
      "unstructured": "Y. V.Mikhaylik US 7 354 680 B2 2008.",
      "DOI": "10.1016/j.jnoncrysol.2007.08.087"
    },
    {
      "key": "e_1_2_6_15_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.electacta.2006.08.016"
    },
    {
      "key": "e_1_2_6_16_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.3390/en5125190"
    },
    {
      "key": "e_1_2_6_17_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.electacta.2012.03.081"
    },
    {
      "key": "e_1_2_6_18_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201107817"
    },
    {
      "key": "e_1_2_6_19_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nmat2460"
    },
    {
      "key": "e_1_2_6_20_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c1ee01219c"
    },
    {
      "key": "e_1_2_6_21_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200907324"
    },
    {
      "key": "e_1_2_6_22_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nl100504q"
    },
    {
      "key": "e_1_2_6_23_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.elecom.2011.10.020"
    },
    {
      "key": "e_1_2_6_24_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nn303393p"
    },
    {
      "key": "e_1_2_6_25_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.2160429"
    },
    {
      "key": "e_1_2_6_26_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/la300306v"
    },
    {
      "key": "e_1_2_6_27_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.2054777"
    },
    {
      "key": "e_1_2_6_28_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0008-6223(00)00237-2"
    },
    {
      "key": "e_1_2_6_29_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.201209849"
    },
    {
      "key": "e_1_2_6_30_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1039/c2cc35112a"
    },
    {
      "key": "e_1_2_6_31_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0378-7753(98)00128-1"
    },
    {
      "key": "e_1_2_6_32_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.electacta.2012.07.118"
    },
    {
      "key": "e_1_2_6_33_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.1806394"
    },
    {
      "key": "e_1_2_6_34_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1149/1.1838585"
    },
    {
      "key": "e_1_2_6_35_1",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/ange.200504327"
    },
    {
      "key": "e_1_2_6_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/anie.200504327"
    }
  ],
  "container-title": "Advanced Functional Materials",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadfm.201302169",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.201302169",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        27
      ]
    ],
    "date-time": "2023-10-27T21:58:57Z",
    "timestamp": 1698443937000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/adfm.201302169"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2013,
        8,
        27
      ]
    ]
  },
  "references-count": 36,
  "journal-issue": {
    "issue": "9",
    "published-print": {
      "date-parts": [
        [
          2014,
          3
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/adfm.201302169"
  ],
  "URL": "http://dx.doi.org/10.1002/adfm.201302169",
  "relation": {},
  "ISSN": [
    "1616-301X",
    "1616-3028"
  ],
  "subject": [],
  "container-title-short": "Adv Funct Materials",
  "published": {
    "date-parts": [
      [
        2013,
        8,
        27
      ]
    ]
  }
}