DOI: 10.1002/adfm.201203491. Functional Free‐Standing Graphene Honeycomb Films

Functional Free‐Standing Graphene Honeycomb Films

10.1002/adfm.201203491

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

AbstractFabricating free‐standing, three‐dimensional (3D) ordered porous graphene structure can service a wide range of functional materials such as environmentally friendly materials for antibacterial medical applications and efficient solar harvesting devices. A scalable solution processable strategy is developed to create such free‐standing hierarchical porous structures composed of functionalized graphene sheets via an “on water spreading” method. The free‐standing film shows a large area uniform honeycomb structure and can be transferred onto any substrate of interest. The graphene‐based free‐standing honeycomb films exhibit superior broad spectrum antibacterial activity as confirmed using green fluorescent protein labeled Pseudomonas aeruginosa PAO1 and Escherichia coli as model pathogens. Functional nanoparticles such as titanium dioxide (TiO2) nanoparticles can be easily introduced into conductive graphene‐based scaffolds by premixing. The formed composite honeycomb film electrode shows a fast, stable, and completely reversible photocurrent response accompanying each switch‐on and switch‐off event. The graphene‐based honeycomb scaffold enhances the light‐harvesting efficiency and improves the photoelectric conversion behavior; the photocurrent of the composite film is about two times as high as that of the pure TiO2 film electrode. Such composite porous films combining remarkably good electrochemical performance of graphene, a large electrode/electrolyte contact area, and excellent stability during the photo‐conversion process hold promise for further applications in water treatment and solar energy conversion.

Bibliography

Yin, S., Goldovsky, Y., Herzberg, M., Liu, L., Sun, H., Zhang, Y., Meng, F., Cao, X., Sun, D. D., Chen, H., Kushmaro, A., & Chen, X. (2013). Functional FreeâStanding Graphene Honeycomb Films. Advanced Functional Materials, 23(23), 2972â2978. Portico.

Authors 12

Shengyan Yin (first)
Yulia Goldovsky (additional)
Moshe Herzberg (additional)
Lei Liu (additional)
Hang Sun (additional)
Yanyan Zhang (additional)
Fanben Meng (additional)
Xuebo Cao (additional)
Darren D. Sun (additional)
Hongyu Chen (additional)
Ariel Kushmaro (additional)
Xiaodong Chen (additional)

References 59 Referenced 120

10.1002/anie.201006240
10.1038/srep00427
10.1002/smll.201101594
10.1002/adma.201104993
10.1021/nn101187z
10.1002/smll.201101396
10.1021/ja901105a
10.1021/nn901850u
10.1021/nl3012853
10.1038/nmat1967
10.1038/srep00166
10.1002/adma.201200197
10.1038/nature06016
10.1021/nl801301a
10.1021/ja806262m
10.1021/la900126g
10.1021/nl803279t
10.1002/smll.201102614
10.1021/nn900582u
10.1021/nn2001728
10.1038/nature09540
10.1038/nmat1655
10.1038/nmat1212
10.1002/adma.201201978
10.1002/cphc.200600393
10.1021/nn100449w
10.1021/nn901587x
10.1021/nn901660v
10.1038/nature04969
10.1021/nl8035367
10.1002/adma.201004715
10.1038/nmat1110
10.1038/nmat1980
10.1002/smll.201200924
10.1002/adma.201003753
10.1021/la011451f
10.1002/adma.200501131
10.1073/pnas.0808608105
10.1021/nn101097v
10.1002/adma.200800757
10.1021/la062670
10.1038/nmat2099
10.1021/bm7004627
10.1038/nnano.2008.68
10.1021/es7032718
10.1021/jp908613u
10.1002/adfm.201001391
{'key': 'e_1_2_6_27_2', 'first-page': '75384', 'author': 'Kong F.‐T.', 'year': '2007', 'journal-title': 'Adv. Optoelectron.'} / Adv. Optoelectron. by Kong F.‐T. (2007)
10.1021/ja804852z
10.1021/nn800174y
10.1021/nl0627238
10.1039/b511911a
10.1016/j.carbon.2007.02.034
10.1021/la102806v
10.1021/jp908233h
10.1038/nature07719
10.1021/nl2029859
10.1021/ja01539a017
10.1038/nnano.2009.58

Dates

Type	When
Created	12 years, 7 months ago (Jan. 17, 2013, 5:56 a.m.)
Deposited	1 year, 10 months ago (Oct. 11, 2023, 7:44 a.m.)
Indexed	3 days, 6 hours ago (Aug. 19, 2025, 6:47 a.m.)
Issued	12 years, 7 months ago (Jan. 17, 2013)
Published	12 years, 7 months ago (Jan. 17, 2013)
Published Online	12 years, 7 months ago (Jan. 17, 2013)
Published Print	12 years, 2 months ago (June 20, 2013)

Funders 0

None

BibTeX

@article{Yin_2013, title={Functional Free‐Standing Graphene Honeycomb Films}, volume={23}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.201203491}, DOI={10.1002/adfm.201203491}, number={23}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Yin, Shengyan and Goldovsky, Yulia and Herzberg, Moshe and Liu, Lei and Sun, Hang and Zhang, Yanyan and Meng, Fanben and Cao, Xuebo and Sun, Darren D. and Chen, Hongyu and Kushmaro, Ariel and Chen, Xiaodong}, year={2013}, month=jan, pages={2972–2978} }

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