Abstract
AbstractAn easy design route via simple evaporation is reported for macroscopic mosaic thin films comprising the quaternary system ofdl‐lysine·HCl, poly(acrylic acid), water, and EtOH. By depositing droplets of the quaternary dispersions onto hydrophilic cover slips, the formation of macroscopic crack‐free mosaic mesocrystal thin films are produced. The formation follows a multistage crystallization process, which includes the formation of a polymer‐induced liquid‐precursor (PILP) phase, the formation of spherulitic thin films, and the recrystallization of mosaic mesocrystal thin films. A slow cooling rate is noted to be beneficial for the mesocrystal thin films, enabling the films to be crack‐free and to display low surface roughness at the nanoscale.
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Dates
Type | When |
---|---|
Created | 12 years, 10 months ago (Oct. 23, 2012, 5:11 a.m.) |
Deposited | 1 year, 3 months ago (April 30, 2024, 12:50 p.m.) |
Indexed | 1 year, 3 months ago (April 30, 2024, 1:10 p.m.) |
Issued | 12 years, 10 months ago (Oct. 23, 2012) |
Published | 12 years, 10 months ago (Oct. 23, 2012) |
Published Online | 12 years, 10 months ago (Oct. 23, 2012) |
Published Print | 12 years, 5 months ago (March 25, 2013) |
@article{Jiang_2012, title={Microdomain Transformations in Mosaic Mesocrystal Thin Films}, volume={23}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.201202294}, DOI={10.1002/adfm.201202294}, number={12}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Jiang, Yuan and Gong, Haofei and Grzywa, Maciej and Volkmer, Dirk and Gower, Laurie and Cölfen, Helmut}, year={2012}, month=oct, pages={1547–1555} }