DOI: 10.1002/adfm.201201847. Carbonyl‐<i>β</i>‐Cyclodextrin as a Novel Binder for Sulfur Composite Cathodes in Rechargeable Lithium Batteries

Carbonyl‐β‐Cyclodextrin as a Novel Binder for Sulfur Composite Cathodes in Rechargeable Lithium Batteries

10.1002/adfm.201201847

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

AbstractAs one of the essential components in electrodes, the binder affects the performance of a rechargeable battery. By modifying β‐cyclodextrin (β‐CD), an appropriate binder for sulfur composite cathodes is identified. Through a partial oxidation reaction in H2O2 solution, β‐CD is successfully modified to carbonyl‐β‐cyclodextrin (C‐β‐CD), which exhibits a water solubility ca. 100 times that of β‐CD at room temperature. C‐β‐CD possesses the typical properties of an aqueous binder: strong bonding strength, high solubility in water, moderate viscosity, and wide electrochemical windows. Sulfur composite cathodes with C‐β‐CD as the binder demonstrate a high reversible capacity of 694.2 mA h g(composite)−1 and 1542.7 mA h g(sulfur)−1, with a sulfur utilization approaching 92.2%. The discharge capacity remains at 1456 mA h g(sulfur)−1 after 50 cycles, which is much higher than that of the cathode with unmodified β‐CD as binder. Combined with its low cost and environmental benignity, C‐β‐CD is a promising binder for sulfur cathodes in rechargeable lithium batteries with high electrochemical performance.

Bibliography

Wang, J., Yao, Z., Monroe, C. W., Yang, J., & Nuli, Y. (2012). CarbonylâÎ²âCyclodextrin as a Novel Binder for Sulfur Composite Cathodes in Rechargeable Lithium Batteries. Advanced Functional Materials, 23(9), 1194â1201. Portico.

Authors 5

Jiulin Wang (first)
Zhendong Yao (additional)
Charles W. Monroe (additional)
Jun Yang (additional)
Yanna Nuli (additional)

References 46 Referenced 256

10.1021/cr020730k
10.1039/c1ee01388b
10.1038/nmat3191
10.1016/S0378-7753(00)00432-8
10.1039/b925751a
10.1039/c1ee01219c
10.1149/1.1806394
10.1021/jp1114724
10.1016/j.elecom.2008.09.012
10.1002/adma.201103392
10.1038/nmat2460
10.1002/anie.201100637
10.1039/c002639e
10.1021/cm902050j
10.1016/j.jpowsour.2011.11.074
10.1039/c1ee02256c
10.1021/nl2027684
10.1021/nl200658a
10.1021/ja206955k
10.1021/nl100504q
10.1002/anie.200907324
10.1149/1.3291976
10.1039/b918727h
10.1126/science.1209150
10.1016/j.elecom.2006.09.013
10.1016/j.jpowsour.2003.12.028
10.1016/j.jallcom.2006.02.098
10.1149/1.1815153
10.1002/adma.200306075
10.1016/j.jpowsour.2011.12.061
{'key': 'e_1_2_7_31_2', 'first-page': 'A10', 'volume': '8', 'author': 'Liu W.', 'year': '2005', 'journal-title': 'Electrochem. Solid‐State Lett.'} / Electrochem. Solid‐State Lett. by Liu W. (2005)
10.1016/j.electacta.2008.05.022
10.1016/j.elecom.2008.04.016
10.1149/1.3299323
10.1002/chem.201003523
10.3109/03639049009058543
10.1021/cr970012b
10.1016/0021-9673(94)80579-2
10.1016/j.elecom.2007.12.015
10.1016/j.jpowsour.2006.01.054
10.1039/c2ee03495f
10.1002/adfm.200304284
10.1002/1521-4095(20020705)14:13/14<963::AID-ADMA963>3.0.CO;2-P
10.1021/jp207714c
10.1016/j.jpowsour.2008.07.034
10.1002/adma.200800627

Dates

Type	When
Created	12 years, 10 months ago (Oct. 4, 2012, 4:15 a.m.)
Deposited	1 year, 10 months ago (Oct. 11, 2023, 3:11 a.m.)
Indexed	2 weeks, 2 days ago (Aug. 5, 2025, 8:19 a.m.)
Issued	12 years, 10 months ago (Oct. 4, 2012)
Published	12 years, 10 months ago (Oct. 4, 2012)
Published Online	12 years, 10 months ago (Oct. 4, 2012)
Published Print	12 years, 5 months ago (March 6, 2013)

Funders 0

None

BibTeX

@article{Wang_2012, title={Carbonyl‐β‐Cyclodextrin as a Novel Binder for Sulfur Composite Cathodes in Rechargeable Lithium Batteries}, volume={23}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.201201847}, DOI={10.1002/adfm.201201847}, number={9}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Wang, Jiulin and Yao, Zhendong and Monroe, Charles W. and Yang, Jun and Nuli, Yanna}, year={2012}, month=oct, pages={1194–1201} }

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