Abstract
Abstract“Graphitic” (g)‐C3N4 with a layered structure has the potential of forming graphene‐like nanosheets with unusual physicochemical properties due to weak van der Waals forces between layers. Herein is shown that g‐C3N4 nanosheets with a thickness of around 2 nm can be easily obtained by a simple top‐down strategy, namely, thermal oxidation etching of bulk g‐C3N4 in air. Compared to the bulk g‐C3N4, the highly anisotropic 2D‐nanosheets possess a high specific surface area of 306 m2 g−1, a larger bandgap (by 0.2 eV), improved electron transport ability along the in‐plane direction, and increased lifetime of photoexcited charge carriers because of the quantum confinement effect. As a consequence, the photocatalytic activities of g‐C3N4 nanosheets have been remarkably improved in terms of •OH radical generation and photocatalytic hydrogen evolution.
References
50
Referenced
3,357
10.1021/cr00033a004
10.1021/cr00035a013
10.1039/b822385h
10.1039/c0cs00211a
10.1021/cr900075v
10.1039/B909930A
10.1039/c1cc10665a
10.1039/B800489G
10.1021/ja027751g
10.1038/414625a
10.1038/440295a
10.1038/nmat2780
10.1021/cr1001645
10.1126/science.1200448
10.1021/cm7024203
10.1039/b800274f
10.1038/nmat2317
10.1021/jp809119m
10.1002/adma.200802627
10.1002/anie.201101182
10.1002/anie.201000120
10.1021/ja103798k
10.1021/ja101749y
10.1039/C0EE00418A
10.1021/jp301026y
10.1039/c1ee01400e
10.1039/c0ee00825g
10.1039/c0cp00611d
10.1039/B914110C
10.1016/j.ijhydene.2011.08.052
10.1021/ja809307s
10.1021/cm201688v
10.1021/ja960073b
10.1021/ja021364p
10.1038/nmat3145
10.1038/nmat1849
10.1039/c0jm03390a
10.1039/b820483g
10.1002/adfm.200500849
10.1021/ja01539a017
10.1002/chem.200601759
10.1002/adma.200401756
10.1126/science.271.5251.933
10.1021/la015685a
10.1002/adma.200802201
10.1021/cr00035a013
10.1021/cr00033a004
10.1039/c0cy00029a
10.1039/B919895D
10.1002/anie.201006057
Dates
Type | When |
---|---|
Created | 13 years, 1 month ago (July 5, 2012, 8:23 a.m.) |
Deposited | 1 year, 10 months ago (Oct. 10, 2023, 5:48 p.m.) |
Indexed | 37 minutes ago (Aug. 29, 2025, 4:45 p.m.) |
Issued | 13 years, 1 month ago (July 5, 2012) |
Published | 13 years, 1 month ago (July 5, 2012) |
Published Online | 13 years, 1 month ago (July 5, 2012) |
Published Print | 12 years, 9 months ago (Nov. 21, 2012) |
@article{Niu_2012, title={Graphene‐Like Carbon Nitride Nanosheets for Improved Photocatalytic Activities}, volume={22}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.201200922}, DOI={10.1002/adfm.201200922}, number={22}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Niu, Ping and Zhang, Lili and Liu, Gang and Cheng, Hui‐Ming}, year={2012}, month=jul, pages={4763–4770} }