DOI: 10.1002/adfm.201102878. Facile Synthesis of Monodisperse Mesoporous Zirconium Titanium Oxide Microspheres with Varying Compositions and High Surface Areas for Heavy Metal Ion Sequestration

Facile Synthesis of Monodisperse Mesoporous Zirconium Titanium Oxide Microspheres with Varying Compositions and High Surface Areas for Heavy Metal Ion Sequestration

10.1002/adfm.201102878

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

AbstractMonodisperse mesoporous zirconium titanium oxide microspheres with varying compositions (Zr content from 0 to 100%), high surface areas (up to 413 m2/g) and well‐interconnected mesopores are synthesized via a combined sol–gel self‐assembly and solvothermal process. Surface areas, pore diameters, crystallinity and mesostructures of the products are controlled by changing the composition of the microspheres. The resulting mesoporous microspheres are tested as adsorbents to remove Cr (VI) anions from solution and the binary oxides show very high adsorption capacities (>25.40 mg/g, that is 0.49 mmol/g) in contrast to previously reported oxides (4.25 mg/g for TiO2, 4.47 mg/g for α‐Fe2O3, 5.8 mg/g for CeO2). The maximum adsorption capacities of the mesoporous microspheres of varying compositions correlate with the amount of surface hydroxyl groups on the materials. A maximum adsorption capacity of 29.46 mg/g (0.57 mmol/g) is achieved on the microspheres containing 30% Zr due to abundant active hydroxyl groups for heavy metal ion adsorption. Owing to their integrated features (including variable compositions, high specific surface area, tunable pore size and monodisperse grain size) as well as specific acid‐base surface properties, such mesoporous zirconium titanium oxide microspheres are also expected to have potential either as catalysts or catalyst supports for industrial applications.

Bibliography

Chen, D., Cao, L., Hanley, T. L., & Caruso, R. A. (2012). Facile Synthesis of Monodisperse Mesoporous Zirconium Titanium Oxide Microspheres with Varying Compositions and High Surface Areas for Heavy Metal Ion Sequestration. Advanced Functional Materials, 22(9), 1966â1971. Portico.

Authors 4

Dehong Chen (first)
Lu Cao (additional)
Tracey L. Hanley (additional)
Rachel A. Caruso (additional)

References 38 Referenced 75

10.1021/cr0500535
10.1038/nprot.2007.261
10.1081/CR-200057488
10.1038/35104607
10.1002/adma.200802603
10.1002/adma.200701507
10.1021/nn1010396
10.1002/adfm.200902218
10.1002/adma.200702055
10.1016/j.jssc.2005.10.032
10.1002/adma.200502568
10.1016/S0022-3115(99)00200-7
10.1016/S0149-1970(97)00061-9
10.1166/jnn.2008.18436
10.1016/j.apcata.2004.01.015
10.1021/la804030h
10.1021/la801464s
10.1021/la9015299
10.1021/la801490k
{'key': 'e_1_2_7_20_2', 'first-page': '1256', 'volume': '130', 'author': 'Pan J. H.', 'year': '2008', 'journal-title': 'J. Am. Chem. Soc.'} / J. Am. Chem. Soc. by Pan J. H. (2008)
10.1006/jcis.1999.6504
10.1016/j.micromeso.2007.01.024
10.1021/jp067109z
10.1016/j.micromeso.2009.05.006
10.1002/adma.200800623
10.1016/j.jhazmat.2005.10.041
US Environmental Protection Agency (EPA) method 7196A Chromium Hexavalent (Colorimetric) http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/7196a.pdf.
10.1002/adma.200501018
10.1021/ja070908q
10.1007/978-1-4020-2303-3
10.1016/S0043-1354(00)00098-1
10.1016/S0001-8686(02)00080-5
10.1081/DIS-120014021
{'key': 'e_1_2_7_34_2', 'volume-title': 'Chemistry of the Solid‐Water Interface: Processes at the Mineral‐Water and Particle‐Water Interface in Natural Systems', 'author': 'Stumm W.', 'year': '1992'} / Chemistry of the Solid‐Water Interface: Processes at the Mineral‐Water and Particle‐Water Interface in Natural Systems by Stumm W. (1992)
10.1021/la025785w
10.1021/ja100040p
10.1021/cr0200062
10.1021/cm050209h

Dates

Type	When
Created	13 years, 6 months ago (Feb. 16, 2012, 3:21 a.m.)
Deposited	1 year, 10 months ago (Oct. 11, 2023, 1:44 p.m.)
Indexed	11 months, 2 weeks ago (Sept. 15, 2024, 9:18 p.m.)
Issued	13 years, 6 months ago (Feb. 16, 2012)
Published	13 years, 6 months ago (Feb. 16, 2012)
Published Online	13 years, 6 months ago (Feb. 16, 2012)
Published Print	13 years, 3 months ago (May 9, 2012)

Funders 0

None

BibTeX

@article{Chen_2012, title={Facile Synthesis of Monodisperse Mesoporous Zirconium Titanium Oxide Microspheres with Varying Compositions and High Surface Areas for Heavy Metal Ion Sequestration}, volume={22}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.201102878}, DOI={10.1002/adfm.201102878}, number={9}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Chen, Dehong and Cao, Lu and Hanley, Tracey L. and Caruso, Rachel A.}, year={2012}, month=feb, pages={1966–1971} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        9,
        16
      ]
    ],
    "date-time": "2024-09-16T01:18:17Z",
    "timestamp": 1726449497332
  },
  "reference-count": 38,
  "publisher": "Wiley",
  "issue": "9",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2012,
            2,
            16
          ]
        ],
        "date-time": "2012-02-16T00:00:00Z",
        "timestamp": 1329350400000
      },
      "content-version": "vor",
      "delay-in-days": 0,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2012,
        5,
        9
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Monodisperse mesoporous zirconium titanium oxide microspheres with varying compositions (Zr content from 0 to 100%), high surface areas (up to 413 m<jats:sup>2</jats:sup>/g) and well\u2010interconnected mesopores are synthesized via a combined sol\u2013gel self\u2010assembly and solvothermal process. Surface areas, pore diameters, crystallinity and mesostructures of the products are controlled by changing the composition of the microspheres. The resulting mesoporous microspheres are tested as adsorbents to remove Cr (VI) anions from solution and the binary oxides show very high adsorption capacities (&gt;25.40 mg/g, that is 0.49 mmol/g) in contrast to previously reported oxides (4.25 mg/g for TiO<jats:sub>2</jats:sub>, 4.47 mg/g for \u03b1\u2010Fe<jats:sub>2</jats:sub>O<jats:sub>3</jats:sub>, 5.8 mg/g for CeO<jats:sub>2</jats:sub>). The maximum adsorption capacities of the mesoporous microspheres of varying compositions correlate with the amount of surface hydroxyl groups on the materials. A maximum adsorption capacity of 29.46 mg/g (0.57 mmol/g) is achieved on the microspheres containing 30% Zr due to abundant active hydroxyl groups for heavy metal ion adsorption. Owing to their integrated features (including variable compositions, high specific surface area, tunable pore size and monodisperse grain size) as well as specific acid\u2010base surface properties, such mesoporous zirconium titanium oxide microspheres are also expected to have potential either as catalysts or catalyst supports for industrial applications.</jats:p>",
  "DOI": "10.1002/adfm.201102878",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2012,
        2,
        16
      ]
    ],
    "date-time": "2012-02-16T08:21:29Z",
    "timestamp": 1329380489000
  },
  "page": "1966-1971",
  "source": "Crossref",
  "is-referenced-by-count": 75,
  "title": "Facile Synthesis of Monodisperse Mesoporous Zirconium Titanium Oxide Microspheres with Varying Compositions and High Surface Areas for Heavy Metal Ion Sequestration",
  "prefix": "10.1002",
  "volume": "22",
  "author": [
    {
      "given": "Dehong",
      "family": "Chen",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Lu",
      "family": "Cao",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Tracey L.",
      "family": "Hanley",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Rachel A.",
      "family": "Caruso",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2012,
        2,
        16
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_7_1_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr0500535"
    },
    {
      "key": "e_1_2_7_2_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/nprot.2007.261"
    },
    {
      "key": "e_1_2_7_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1081/CR-200057488"
    },
    {
      "key": "e_1_2_7_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/35104607"
    },
    {
      "key": "e_1_2_7_5_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.200802603"
    },
    {
      "key": "e_1_2_7_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.200701507"
    },
    {
      "key": "e_1_2_7_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/nn1010396"
    },
    {
      "key": "e_1_2_7_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adfm.200902218"
    },
    {
      "key": "e_1_2_7_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.200702055"
    },
    {
      "key": "e_1_2_7_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jssc.2005.10.032"
    },
    {
      "key": "e_1_2_7_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.200502568"
    },
    {
      "key": "e_1_2_7_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0022-3115(99)00200-7"
    },
    {
      "key": "e_1_2_7_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0149-1970(97)00061-9"
    },
    {
      "key": "e_1_2_7_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1166/jnn.2008.18436"
    },
    {
      "key": "e_1_2_7_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.apcata.2004.01.015"
    },
    {
      "key": "e_1_2_7_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/la804030h"
    },
    {
      "key": "e_1_2_7_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/la801464s"
    },
    {
      "key": "e_1_2_7_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/la9015299"
    },
    {
      "key": "e_1_2_7_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/la801490k"
    },
    {
      "key": "e_1_2_7_20_2",
      "first-page": "1256",
      "volume": "130",
      "author": "Pan J. H.",
      "year": "2008",
      "journal-title": "J. Am. Chem. Soc."
    },
    {
      "key": "e_1_2_7_21_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1006/jcis.1999.6504"
    },
    {
      "key": "e_1_2_7_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.micromeso.2007.01.024"
    },
    {
      "key": "e_1_2_7_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/jp067109z"
    },
    {
      "key": "e_1_2_7_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.micromeso.2009.05.006"
    },
    {
      "key": "e_1_2_7_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.200800623"
    },
    {
      "key": "e_1_2_7_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/j.jhazmat.2005.10.041"
    },
    {
      "key": "e_1_2_7_27_2",
      "unstructured": "US Environmental Protection Agency (EPA) method 7196A Chromium Hexavalent (Colorimetric) http://www.epa.gov/osw/hazard/testmethods/sw846/pdfs/7196a.pdf."
    },
    {
      "key": "e_1_2_7_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/adma.200501018"
    },
    {
      "key": "e_1_2_7_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja070908q"
    },
    {
      "key": "e_1_2_7_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/978-1-4020-2303-3"
    },
    {
      "key": "e_1_2_7_31_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0043-1354(00)00098-1"
    },
    {
      "key": "e_1_2_7_32_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0001-8686(02)00080-5"
    },
    {
      "key": "e_1_2_7_33_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1081/DIS-120014021"
    },
    {
      "key": "e_1_2_7_34_2",
      "volume-title": "Chemistry of the Solid\u2010Water Interface: Processes at the Mineral\u2010Water and Particle\u2010Water Interface in Natural Systems",
      "author": "Stumm W.",
      "year": "1992"
    },
    {
      "key": "e_1_2_7_35_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/la025785w"
    },
    {
      "key": "e_1_2_7_36_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ja100040p"
    },
    {
      "key": "e_1_2_7_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cr0200062"
    },
    {
      "key": "e_1_2_7_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/cm050209h"
    }
  ],
  "container-title": "Advanced Functional Materials",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadfm.201102878",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.201102878",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        10,
        11
      ]
    ],
    "date-time": "2023-10-11T17:44:32Z",
    "timestamp": 1697046272000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/adfm.201102878"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2012,
        2,
        16
      ]
    ]
  },
  "references-count": 38,
  "journal-issue": {
    "issue": "9",
    "published-print": {
      "date-parts": [
        [
          2012,
          5,
          9
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/adfm.201102878"
  ],
  "URL": "http://dx.doi.org/10.1002/adfm.201102878",
  "relation": {},
  "ISSN": [
    "1616-301X",
    "1616-3028"
  ],
  "subject": [],
  "container-title-short": "Adv Funct Materials",
  "published": {
    "date-parts": [
      [
        2012,
        2,
        16
      ]
    ]
  }
}