DOI: 10.1002/adfm.200800516. A Triphenylamine Dye Model for the Study of Intramolecular Energy Transfer and Charge Transfer in Dye‐Sensitized Solar Cells

A Triphenylamine Dye Model for the Study of Intramolecular Energy Transfer and Charge Transfer in Dye‐Sensitized Solar Cells

10.1002/adfm.200800516

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

AbstractA novel dye (2TPA‐R), containing two triphenylamine (TPA) units connected by a vinyl group and rhodanine‐3‐acetic acid as the electron acceptor, is designed and synthesized successfully to reveal the working principles of organic dye in dye‐sensitized solar cells (DSSCs). 2TPA and TPA‐R, which consist of two TPA units connected by vinyl and a TPA unit linked with rhodanine‐3‐acetic acid, respectively, are also synthesized as references to study the intramolecular energy transfer (EnT) and charge transfer (ICT) processes of 2TPA‐R in CH2Cl2 solution and on a TiO2 surface. The results suggest that the intramolecular EnT and ICT processes show a positive effect on the performance of DSSCs. However, the flexible structure and less‐adsorbed amount of dye on TiO2 may make it difficult to improve the efficiency of DSSCs. This study on intramolecular EnT and ICT processes acts as a guide for the design and synthesis of efficient organic dyes in the future.

Bibliography

Tian, H., Yang, X., Pan, J., Chen, R., Liu, M., Zhang, Q., Hagfeldt, A., & Sun, L. (2008). A Triphenylamine Dye Model for the Study of Intramolecular Energy Transfer and Charge Transfer in DyeâSensitized Solar Cells. Advanced Functional Materials, 18(21), 3461â3468. Portico.

Authors 8

Haining Tian (first)
Xichuan Yang (additional)
Jingxi Pan (additional)
Ruikui Chen (additional)
Ming Liu (additional)
Qingyu Zhang (additional)
Anders Hagfeldt (additional)
Licheng Sun (additional)

References 36 Referenced 142

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{'key': 'e_1_2_1_16_2', 'volume-title': 'Gaussian03', 'author': 'Frisch M. J.', 'year': '2004'} / Gaussian03 by Frisch M. J. (2004)
10.1002/pip.768

Dates

Type	When
Created	16 years, 9 months ago (Nov. 4, 2008, 1:43 a.m.)
Deposited	1 year, 10 months ago (Sept. 28, 2023, 5:29 p.m.)
Indexed	5 hours, 50 minutes ago (Aug. 28, 2025, 8:41 a.m.)
Issued	16 years, 9 months ago (Nov. 4, 2008)
Published	16 years, 9 months ago (Nov. 4, 2008)
Published Online	16 years, 9 months ago (Nov. 4, 2008)
Published Print	16 years, 9 months ago (Nov. 10, 2008)

Funders 0

None

BibTeX

@article{Tian_2008, title={A Triphenylamine Dye Model for the Study of Intramolecular Energy Transfer and Charge Transfer in Dye‐Sensitized Solar Cells}, volume={18}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.200800516}, DOI={10.1002/adfm.200800516}, number={21}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Tian, Haining and Yang, Xichuan and Pan, Jingxi and Chen, Ruikui and Liu, Ming and Zhang, Qingyu and Hagfeldt, Anders and Sun, Licheng}, year={2008}, month=nov, pages={3461–3468} }

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