DOI: 10.1002/adfm.200800058. Multifunctional Microporous MOFs Exhibiting Gas/Hydrocarbon Adsorption Selectivity, Separation Capability and Three‐Dimensional Magnetic Ordering

Multifunctional Microporous MOFs Exhibiting Gas/Hydrocarbon Adsorption Selectivity, Separation Capability and Three‐Dimensional Magnetic Ordering

10.1002/adfm.200800058

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

AbstractMicroporous materials [M3(HCOO)6] · DMF (M = Mn, Co, Ni) were synthesized solvothermally and structurally characterized by single crystal and powder X‐ray diffraction methods. The metal network exhibits diamondoid connectivity and the overall framework gives rise to zigzag channels along the b axis where guest dimethylformamide molecules reside. The effective pore size of these channels is ∼5–6 Å. The materials feature high thermal stability and permanent porosity with relatively small pore diameters which are attributed to the extensive strong dative bonding between the metal centers and formate molecules. The title compounds exhibit interesting multi‐fold gas adsorption and magnetic properties. The adsorption study of a series of alcohols, aromatics, and linear hydrocarbons revealed strong control of the adsorbent channel structures on their adsorption capacity and selectivity. The study also indicated possibility of using these materials for separation of close boiling chemicals (e.g., ethylbenzene and p‐xylene) via pressure swing adsorption (PSA) process and molecules with different diffusion parameters via kinetic‐based process. Three‐dimensional spontaneous magnetic ordering was found in all three network structures investigated and at ground states they behave somewhat like soft magnets.

Bibliography

Li, K., Olson, D. H., Lee, J. Y., Bi, W., Wu, K., Yuen, T., Xu, Q., & Li, J. (2008). Multifunctional Microporous MOFs Exhibiting Gas/Hydrocarbon Adsorption Selectivity, Separation Capability and ThreeâDimensional Magnetic Ordering. Advanced Functional Materials, 18(15), 2205â2214. Portico.

Authors 8

Kunhao Li (first)
David H. Olson (additional)
Jeong Yong Lee (additional)
Wenhua Bi (additional)
Ke Wu (additional)
Tan Yuen (additional)
Qiang Xu (additional)
Jing Li (additional)

References 46 Referenced 167

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Dates

Type	When
Created	17 years, 1 month ago (July 18, 2008, 6:11 a.m.)
Deposited	1 year, 9 months ago (Nov. 14, 2023, 3:52 p.m.)
Indexed	1 month ago (July 19, 2025, 11:49 p.m.)
Issued	17 years ago (Aug. 6, 2008)
Published	17 years ago (Aug. 6, 2008)
Published Online	17 years ago (Aug. 6, 2008)
Published Print	17 years ago (Aug. 11, 2008)

Funders 0

None

BibTeX

@article{Li_2008, title={Multifunctional Microporous MOFs Exhibiting Gas/Hydrocarbon Adsorption Selectivity, Separation Capability and Three‐Dimensional Magnetic Ordering}, volume={18}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.200800058}, DOI={10.1002/adfm.200800058}, number={15}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Li, Kunhao and Olson, David H. and Lee, Jeong Yong and Bi, Wenhua and Wu, Ke and Yuen, Tan and Xu, Qiang and Li, Jing}, year={2008}, month=aug, pages={2205–2214} }

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