DOI: 10.1002/adfm.200600944. Microporous Metal–Organic Frameworks with High Gas Sorption and Separation Capacity

Microporous Metal–Organic Frameworks with High Gas Sorption and Separation Capacity

10.1002/adfm.200600944

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

AbstractThe design, synthesis, and structural characterization of two microporous metal–organic framework structures, [M(bdc)(ted)0.5]·2 DMF·0.2 H2O (M = Zn (1), Cu (2); H2bdc = 1,4‐benzenedicarboxylic acid; ted = triethylenediamine; DMF: N,N‐dimethylformamide) is reported. The pore characteristics and gas sorption properties of these compounds are investigated at cryogenic temperatures, room temperature, and higher temperatures by experimentally measuring argon, hydrogen, and selected hydrocarbon adsorption/desorption isotherms. These studies show that both compounds are highly porous with a pore volume of 0.65 (1) and 0.52 cm3 g– 1 (2). The amount of the hydrogen uptake, 2.1 wt % (1) and 1.8 wt % (2) at 77 K (1 atm; 1 atm = 101 325 Pa), places them among the group of metal–organic frameworks (MOFs) having the highest H2 sorption capacity. [Zn(bdc)(ted)0.5]·2 DMF·0.2 H2O adsorbs a very large amount of hydrocarbons, including methanol, ethanol, dimethylether (DME), n‐hexane, cyclohexane, and benzene, giving the highest sorption values among all metal–organic based porous materials reported to date. In addition, these materials hold great promise for gas separation.

Bibliography

Lee, J. Y., Olson, D. H., Pan, L., Emge, T. J., & Li, J. (2007). Microporous MetalâOrganic Frameworks with High Gas Sorption and Separation Capacity. Advanced Functional Materials, 17(8), 1255â1262. Portico.

Authors 5

J. Y. Lee (first)
D. H. Olson (additional)
L. Pan (additional)
T. J. Emge (additional)
J. Li (additional)

References 42 Referenced 326

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Crystal data for [Zn(bdc)(ted)0.5]·2 DMF·0.2 H2O (1): weight‐average molecular weightMw = 432.69 g mol–1 tetragonal P4/ncc(no. 130) a = 14.8999(3) c = 19.1369(2) Å V = 4248.4(2) Å3 Z = 8 T = 100 K density (calcd) = 1.353 mg m–3 MoKα radiation μ = 11.91 cm–1 colorless block crystal size = 0.13 mm × 0.11 mm × 0.03 mm total number of reflections 24 335 (3119 uniqueR(int) = 0.055) R1= 0.044 (2113 data withI > 2σ(I)) wR2= 0.1368 (all data) GOF = 1.008 (all data). CCDC 240928 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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The surface area and pore volume of the Cu compound2are notably smaller compared with those of1. We believe this is likely due to the difference in the sample quality.
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Dates

Type	When
Created	18 years, 4 months ago (April 3, 2007, 7:46 a.m.)
Deposited	1 year, 11 months ago (Sept. 11, 2023, 3:33 p.m.)
Indexed	1 month, 3 weeks ago (July 6, 2025, 10:05 a.m.)
Issued	18 years, 4 months ago (April 3, 2007)
Published	18 years, 4 months ago (April 3, 2007)
Published Online	18 years, 4 months ago (April 3, 2007)
Published Print	18 years, 3 months ago (May 21, 2007)

Funders 1

National Energy Technology Laboratory 10.13039/100013165
Region: Americas
gov (Research institutes and centers)
Labels13
1. U.S. Department of Energy National Energy Technology Laboratory
2. U.S. Department of Energy's National Energy Technology Lab
3. United States National Energy Technology Laboratory
4. U.S. Dept. of Energy-National Energy Technology Laboratory
5. United States Department of Energy's National Energy Technology Laboratory
6. DOE's National Energy Technology Laboratory
7. National Energy Technology Laboratory, U.S. Department of Energy
8. National Energy Technology Lab
9. DOE/National Energy Technology Laboratory
10. U.S. Department of Energy-National Energy Technology Laboratory
11. U.S. Department of Energy's National Energy Technology Laboratory
12. US Department of Energy's National Energy Technology Laboratory
13. NETL
Awards1
1. DE-FC26-05NT42446

BibTeX

@article{Lee_2007, title={Microporous Metal–Organic Frameworks with High Gas Sorption and Separation Capacity}, volume={17}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.200600944}, DOI={10.1002/adfm.200600944}, number={8}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Lee, J. Y. and Olson, D. H. and Pan, L. and Emge, T. J. and Li, J.}, year={2007}, month=apr, pages={1255–1262} }

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