DOI: 10.1002/adfm.200600416. Platinum Nanoparticle Clusters Immobilized on Multiwalled Carbon Nanotubes: Electrodeposition and Enhanced Electrocatalytic Activity for Methanol Oxidation

Platinum Nanoparticle Clusters Immobilized on Multiwalled Carbon Nanotubes: Electrodeposition and Enhanced Electrocatalytic Activity for Methanol Oxidation

10.1002/adfm.200600416

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

Abstract3D flowerlike Pt nanoparticle clusters are electrodeposited onto multiwalled carbon nanotubes (MWCNTs) by using a three‐step protocol, which is all‐electrochemical and involves a key, second step of a potential pulse sequence. This 3D fractal morphology is in marked contrast to the 2D uniform nanoparticle dispersion of MWCNTs, which is achieved when the second step adopts cyclic voltammetry instead of a potential‐step method. The former is found to exhibit significantly higher electrocatalytic activity and better stability than the latter for oxidation of methanol. These attractive features are attributable to the unique 3D flowerlike structure of Pt nanoparticle clusters on MWCNTs with much higher electrochemically active surface areas. Our work points to a new path for the preparation of 3D Pt/MWCNT nanocomposites, which are promising as electrocatalysts in direct methanol fuel cells.

Bibliography

Zhao, Y., Fan, L., Zhong, H., Li, Y., & Yang, S. (2007). Platinum Nanoparticle Clusters Immobilized on Multiwalled Carbon Nanotubes: Electrodeposition and Enhanced Electrocatalytic Activity for Methanol Oxidation. Advanced Functional Materials, 17(9), 1537â1541. Portico.

Authors 5

Y. Zhao (first)
L. Fan (additional)
H. Zhong (additional)
Y. Li (additional)
S. Yang (additional)

References 28 Referenced 149

10.1002/1615-6854(200107)1:2<133::AID-FUCE133>3.0.CO;2-5
10.1039/b314224h
10.1021/jp0514675
10.1126/science.1060928
10.1021/cen-v075n026.p039
10.1016/S0926-860X(98)00177-X
10.1021/ja026824t
10.1002/adma.19960080212
10.1016/0022-0728(88)87023-2
10.1016/0022-0728(89)80076-2
10.1016/0022-0728(90)85058-D
10.1021/jp0357929
10.1016/j.carbon.2003.10.023
10.1021/jp0461652
10.1002/anie.200501792
10.1021/la052753a
10.1021/cm970364z
10.1021/la0116903
10.1016/0022-0728(94)03659-Q
10.1016/0013-4686(92)85027-I
10.1021/jp046697i
10.1021/nl051834o
10.1021/nl052175i
10.1016/j.jelechem.2004.07.006
10.1021/ac000967l
A. J. Bard L. R. Faulkner Electrochemical Methods: Fundamentals and Applications Wiley New York1980 p. 540.
10.1149/1.2086566
10.1016/S0167-2738(01)00908-0

Dates

Type	When
Created	18 years, 4 months ago (April 24, 2007, 12:10 p.m.)
Deposited	1 year, 11 months ago (Sept. 11, 2023, 3:26 p.m.)
Indexed	2 months, 4 weeks ago (June 6, 2025, 10:29 p.m.)
Issued	18 years, 4 months ago (April 24, 2007)
Published	18 years, 4 months ago (April 24, 2007)
Published Online	18 years, 4 months ago (April 24, 2007)
Published Print	18 years, 2 months ago (June 18, 2007)

Funders 4

NNSF of China 10.13039/501100001809 National Natural Science Foundation of China
Region: Asia
gov (National government)
Labels11
1. Chinese National Science Foundation
2. Natural Science Foundation of China
3. National Science Foundation of China
4. NNSF of China
5. NSF of China
6. 国家自然科学基金委员会
7. National Nature Science Foundation of China
8. Guójiā Zìrán Kēxué Jījīn Wěiyuánhuì
9. NSFC
10. NNSF
11. NNSFC
Awards1
1. 20473014
Major State Basic Research Development Programs
Awards1
1. 2004CB719903
NNSFC-RGC
UGC of Hong Kong
Awards1
1. N_HKUST604/04

BibTeX

@article{Zhao_2007, title={Platinum Nanoparticle Clusters Immobilized on Multiwalled Carbon Nanotubes: Electrodeposition and Enhanced Electrocatalytic Activity for Methanol Oxidation}, volume={17}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.200600416}, DOI={10.1002/adfm.200600416}, number={9}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Zhao, Y. and Fan, L. and Zhong, H. and Li, Y. and Yang, S.}, year={2007}, month=apr, pages={1537–1541} }

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