DOI: 10.1002/adfm.200500168. 2,7‐Carbazolenevinylene‐Based Oligomer Thin‐Film Transistors: High Mobility Through Structural Ordering

2,7‐Carbazolenevinylene‐Based Oligomer Thin‐Film Transistors: High Mobility Through Structural Ordering

10.1002/adfm.200500168

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

AbstractWe have fabricated organic field‐effect transistors based on thin films of 2,7‐carbazole oligomeric semiconductors 1,4‐bis(vinylene‐(N‐hexyl‐2‐carbazole))phenylene (CPC), 1,4‐bis(vinylene‐(N′‐methyl‐7′‐hexyl‐2′‐carbazole))benzene (RCPCR), N‐hexyl‐2,7‐bis(vinylene‐(N‐hexyl‐2‐carbazole))carbazole (CCC), and N‐methyl‐2,7‐bis(vinylene‐(7‐hexyl‐N‐methyl‐2‐carbazole))carbazole (RCCCR). The organic semiconductors are deposited by thermal evaporation on bare and chemically modified silicon dioxide surfaces (SiO2/Si) held at different temperatures varying from 25 to 200 °C during deposition. The resulting thin films have been characterized using UV‐vis and Fourier‐transform infrared spectroscopies, scanning electron microscopy, and X‐ray diffraction, and the observed top‐contact transistor performances have been correlated with thin‐film properties. We found that these new π‐conjugated oligomers can form highly ordered structures and reach high hole mobilities. Devices using CPC as the active semiconductor have exhibited mobilities as high as 0.3 cm2 V–1 s–1 with on/off current ratios of up to 107. These features make CPC and 2,7‐carbazolenevinylene‐based oligomers attractive candidates for device applications.

Bibliography

Drolet, N., Morin, J. âF., Leclerc, N., Wakim, S., Tao, Y., & Leclerc, M. (2005). 2,7âCarbazolenevinyleneâBased Oligomer ThinâFilm Transistors: High Mobility Through Structural Ordering. Advanced Functional Materials, 15(10), 1671â1682. Portico.

Authors 6

N. Drolet (first)
J.‐F. Morin (additional)
N. Leclerc (additional)
S. Wakim (additional)
Y. Tao (additional)
M. Leclerc (additional)

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Dates

Type	When
Created	20 years ago (Sept. 5, 2005, 10:18 a.m.)
Deposited	1 year, 10 months ago (Oct. 12, 2023, 10:51 p.m.)
Indexed	1 year, 1 month ago (July 6, 2024, 3:55 a.m.)
Issued	20 years ago (Sept. 5, 2005)
Published	20 years ago (Sept. 5, 2005)
Published Online	20 years ago (Sept. 5, 2005)
Published Print	19 years, 11 months ago (Oct. 1, 2005)

Funders 0

None

BibTeX

@article{Drolet_2005, title={2,7‐Carbazolenevinylene‐Based Oligomer Thin‐Film Transistors: High Mobility Through Structural Ordering}, volume={15}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.200500168}, DOI={10.1002/adfm.200500168}, number={10}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Drolet, N. and Morin, J.‐F. and Leclerc, N. and Wakim, S. and Tao, Y. and Leclerc, M.}, year={2005}, month=sep, pages={1671–1682} }

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