DOI: 10.1002/adfm.200305034. Composites of Polyacrylonitrile and Multiwalled Carbon Nanotubes Prepared by Gelation/Crystallization from Solution

Composites of Polyacrylonitrile and Multiwalled Carbon Nanotubes Prepared by Gelation/Crystallization from Solution

10.1002/adfm.200305034

Crossref journal-article

Wiley

Advanced Functional Materials (311)

Abstract

AbstractComposite films of polyacrylonitrile (PAN) and multiwalled carbon nanotubes (MWNTs) have been prepared by gelation/crystallization from solution. The contents of MWNTs were 5–10 wt.‐%, measured against PAN. The electrical and mechanical properties have been studied in comparison with those of the homopolymer PAN films prepared from the same method. Furthermore, stabilization and the carbonization have been carried out by using the drawn PAN–MWNTs as a new precursor to prepare carbon films with a cross‐sectional area much larger than that of a commercial carbon fiber (&&num;62; 3000 times). The MWNTs within the PAN matrix promote the formation of a condensed aromatic ladder structure during the stabilization process and play an important role in preparing PAN‐based carbon material with high carbon quality and high mechanical properties. When the stabilized composites with 10 wt.‐% MWNTs are carbonized at 1000 °C, the Young's modulus reaches 37.5 GPa, and the electrical conductivity reaches 102 S cm–1. The carbonized PAN homopolymer does not form an adequately robust bulk film for the mechanical properties to be measured.

Bibliography

Koganemaru, A., Bin, Y., Agari, Y., & Matsuo, M. (2004). Composites of Polyacrylonitrile and Multiwalled Carbon Nanotubes Prepared by Gelation/Crystallization from Solution. Advanced Functional Materials, 14(9), 842â850. Portico.

Authors 4

A. Koganemaru (first)
Y. Bin (additional)
Y. Agari (additional)
M. Matsuo (additional)

References 37 Referenced 62

{'key': 'e_1_2_1_2_2', 'first-page': '157', 'volume': '2', 'author': 'Donnet J. B.', 'year': '1987', 'journal-title': 'Encyclopedia of Physical Science and Technology'} / Encyclopedia of Physical Science and Technology by Donnet J. B. (1987)
10.1016/S0008-6223(97)00126-7
10.1007/BF01160584
10.1080/15321799708014734 / JMS‐REV Macromol. Chem. Phys. by Bajaj P. (1997)
10.1016/S0008-6223(96)00094-2
10.1016/S0008-6223(97)00025-0
10.1016/0008-6223(91)90024-D
10.1016/S0008-6223(01)00116-6
10.1002/app.11415
10.1007/s003390050999
10.1038/381678a0
10.1126/science.277.5334.1971
10.1002/(SICI)1521-4095(199908)11:11<937::AID-ADMA937>3.0.CO;2-9
10.1063/1.126500
10.1557/JMR.2000.0396
10.1126/science.265.5176.1212
10.1063/1.122125
10.1063/1.123330
10.1016/S0009-2614(00)01013-7
Y. Bin M. Kitanaka D. Zhu M. Matsuo Macromolecules in press.
10.1002/1527-2648(200203)4:3<109::AID-ADEM109>3.0.CO;2-5
10.1016/S0009-2614(03)00464-0
10.1007/BF02847554
10.1103/PhysRevB.20.392
10.1021/ma9614095
10.1295/polymj.30.372
10.1016/0008-6223(92)90185-Y
10.1016/0584-8539(85)80105-7
10.1016/0008-6223(88)90070-X
Carbon Fibers Filaments and Composites(Eds: J. L. Figueiredo C. A. Bernardo P. T. K. Baker K. J. Huttinger) Kluwer Academic Publishers New York1989.
Carbon Fiber(Eds: J. B. Donnet T. K. Wang J. C. M. Peng) Marcel Dekker New York1998.
Conductive Polymeric Materials(Ed: H. Sasabe) CMC Publishers Tokyo Japan2000 p. 21.
{'key': 'e_1_2_1_34_2', 'first-page': '272', 'volume': '13', 'author': 'Inokuti H.', 'year': '1963', 'journal-title': 'Kobunshi'} / Kobunshi by Inokuti H. (1963)
R. Saito G. Dresselhaus M. S. Dresselhaus Physical Properties of Carbon Nanotubes Imperial College Press London1999 p. 158. (10.1142/p080)
{'key': 'e_1_2_1_36_2', 'first-page': '431', 'volume': '23', 'author': 'Kobayashi M.', 'year': '1980', 'journal-title': 'Rep. Prog. Polym. Phys. Jpn.'} / Rep. Prog. Polym. Phys. Jpn. by Kobayashi M. (1980)
10.1021/ma00161a041
10.1007/s003960050408

Dates

Type	When
Created	20 years, 11 months ago (Sept. 29, 2004, 8:02 a.m.)
Deposited	1 year, 9 months ago (Nov. 16, 2023, 7:47 p.m.)
Indexed	11 months, 2 weeks ago (Sept. 12, 2024, 8:31 a.m.)
Issued	20 years, 11 months ago (Sept. 1, 2004)
Published	20 years, 11 months ago (Sept. 1, 2004)
Published Online	20 years, 11 months ago (Sept. 29, 2004)
Published Print	20 years, 11 months ago (Sept. 1, 2004)

Funders 0

None

BibTeX

@article{Koganemaru_2004, title={Composites of Polyacrylonitrile and Multiwalled Carbon Nanotubes Prepared by Gelation/Crystallization from Solution}, volume={14}, ISSN={1616-3028}, url={http://dx.doi.org/10.1002/adfm.200305034}, DOI={10.1002/adfm.200305034}, number={9}, journal={Advanced Functional Materials}, publisher={Wiley}, author={Koganemaru, A. and Bin, Y. and Agari, Y. and Matsuo, M.}, year={2004}, month=sep, pages={842–850} }

JSON

{
  "indexed": {
    "date-parts": [
      [
        2024,
        9,
        12
      ]
    ],
    "date-time": "2024-09-12T12:31:16Z",
    "timestamp": 1726144276191
  },
  "reference-count": 37,
  "publisher": "Wiley",
  "issue": "9",
  "license": [
    {
      "start": {
        "date-parts": [
          [
            2004,
            9,
            29
          ]
        ],
        "date-time": "2004-09-29T00:00:00Z",
        "timestamp": 1096416000000
      },
      "content-version": "vor",
      "delay-in-days": 28,
      "URL": "http://onlinelibrary.wiley.com/termsAndConditions#vor"
    }
  ],
  "content-domain": {
    "domain": [],
    "crossmark-restriction": false
  },
  "published-print": {
    "date-parts": [
      [
        2004,
        9
      ]
    ]
  },
  "abstract": "<jats:title>Abstract</jats:title><jats:p>Composite films of polyacrylonitrile (PAN) and multiwalled carbon nanotubes (MWNTs) have been prepared by gelation/crystallization from solution. The contents of MWNTs were 5\u201310\u2009wt.\u2010%, measured against PAN. The electrical and mechanical properties have been studied in comparison with those of the homopolymer PAN films prepared from the same method. Furthermore, stabilization and the carbonization have been carried out by using the drawn PAN\u2013MWNTs as a new precursor to prepare carbon films with a cross\u2010sectional area much larger than that of a commercial carbon fiber (&amp;&amp;num;62;\u20093000 times). The MWNTs within the PAN matrix promote the formation of a condensed aromatic ladder structure during the stabilization process and play an important role in preparing PAN\u2010based carbon material with high carbon quality and high mechanical properties. When the stabilized composites with 10\u2009wt.\u2010% MWNTs are carbonized at 1000\u2009\u00b0C, the Young's modulus reaches 37.5\u2009GPa, and the electrical conductivity reaches 10<jats:sup>2</jats:sup>\u2009S\u2009cm<jats:sup>\u20131</jats:sup>. The carbonized PAN homopolymer does not form an adequately robust bulk film for the mechanical properties to be measured.</jats:p>",
  "DOI": "10.1002/adfm.200305034",
  "type": "journal-article",
  "created": {
    "date-parts": [
      [
        2004,
        9,
        29
      ]
    ],
    "date-time": "2004-09-29T12:02:06Z",
    "timestamp": 1096459326000
  },
  "page": "842-850",
  "source": "Crossref",
  "is-referenced-by-count": 62,
  "title": "Composites of Polyacrylonitrile and Multiwalled Carbon Nanotubes Prepared by Gelation/Crystallization from Solution",
  "prefix": "10.1002",
  "volume": "14",
  "author": [
    {
      "given": "A.",
      "family": "Koganemaru",
      "sequence": "first",
      "affiliation": []
    },
    {
      "given": "Y.",
      "family": "Bin",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "Y.",
      "family": "Agari",
      "sequence": "additional",
      "affiliation": []
    },
    {
      "given": "M.",
      "family": "Matsuo",
      "sequence": "additional",
      "affiliation": []
    }
  ],
  "member": "311",
  "published-online": {
    "date-parts": [
      [
        2004,
        9,
        29
      ]
    ]
  },
  "reference": [
    {
      "key": "e_1_2_1_2_2",
      "first-page": "157",
      "volume": "2",
      "author": "Donnet J. B.",
      "year": "1987",
      "journal-title": "Encyclopedia of Physical Science and Technology"
    },
    {
      "key": "e_1_2_1_3_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0008-6223(97)00126-7"
    },
    {
      "key": "e_1_2_1_4_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF01160584"
    },
    {
      "key": "e_1_2_1_5_2",
      "doi-asserted-by": "crossref",
      "first-page": "9",
      "DOI": "10.1080/15321799708014734",
      "volume": "37",
      "author": "Bajaj P.",
      "year": "1997",
      "journal-title": "JMS\u2010REV Macromol. Chem. Phys."
    },
    {
      "key": "e_1_2_1_6_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0008-6223(96)00094-2"
    },
    {
      "key": "e_1_2_1_7_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0008-6223(97)00025-0"
    },
    {
      "key": "e_1_2_1_8_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0008-6223(91)90024-D"
    },
    {
      "key": "e_1_2_1_9_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0008-6223(01)00116-6"
    },
    {
      "key": "e_1_2_1_10_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/app.11415"
    },
    {
      "key": "e_1_2_1_11_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/s003390050999"
    },
    {
      "key": "e_1_2_1_12_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1038/381678a0"
    },
    {
      "key": "e_1_2_1_13_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.277.5334.1971"
    },
    {
      "key": "e_1_2_1_14_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/(SICI)1521-4095(199908)11:11<937::AID-ADMA937>3.0.CO;2-9"
    },
    {
      "key": "e_1_2_1_15_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.126500"
    },
    {
      "key": "e_1_2_1_16_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1557/JMR.2000.0396"
    },
    {
      "key": "e_1_2_1_17_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1126/science.265.5176.1212"
    },
    {
      "key": "e_1_2_1_18_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.122125"
    },
    {
      "key": "e_1_2_1_19_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1063/1.123330"
    },
    {
      "key": "e_1_2_1_20_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0009-2614(00)01013-7"
    },
    {
      "key": "e_1_2_1_21_2",
      "unstructured": "Y. Bin M. Kitanaka D. Zhu M. Matsuo Macromolecules in press."
    },
    {
      "key": "e_1_2_1_22_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1002/1527-2648(200203)4:3<109::AID-ADEM109>3.0.CO;2-5"
    },
    {
      "key": "e_1_2_1_23_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/S0009-2614(03)00464-0"
    },
    {
      "key": "e_1_2_1_24_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/BF02847554"
    },
    {
      "key": "e_1_2_1_25_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1103/PhysRevB.20.392"
    },
    {
      "key": "e_1_2_1_26_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ma9614095"
    },
    {
      "key": "e_1_2_1_27_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1295/polymj.30.372"
    },
    {
      "key": "e_1_2_1_28_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0008-6223(92)90185-Y"
    },
    {
      "key": "e_1_2_1_29_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0584-8539(85)80105-7"
    },
    {
      "key": "e_1_2_1_30_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1016/0008-6223(88)90070-X"
    },
    {
      "key": "e_1_2_1_31_2",
      "unstructured": "Carbon Fibers Filaments and Composites(Eds: J.\u2009L. Figueiredo C.\u2009A. Bernardo P.\u2009T.\u2009K. Baker K.\u2009J. Huttinger) Kluwer Academic Publishers New York1989."
    },
    {
      "key": "e_1_2_1_32_2",
      "unstructured": "Carbon Fiber(Eds: J.\u2009B. Donnet T.\u2009K. Wang J.\u2009C.\u2009M. Peng) Marcel Dekker New York1998."
    },
    {
      "key": "e_1_2_1_33_2",
      "unstructured": "Conductive Polymeric Materials(Ed: H. Sasabe) CMC Publishers Tokyo Japan2000 p.\u200921."
    },
    {
      "key": "e_1_2_1_34_2",
      "first-page": "272",
      "volume": "13",
      "author": "Inokuti H.",
      "year": "1963",
      "journal-title": "Kobunshi"
    },
    {
      "key": "e_1_2_1_35_2",
      "doi-asserted-by": "crossref",
      "unstructured": "R. Saito G. Dresselhaus M.\u2009S. Dresselhaus Physical Properties of Carbon Nanotubes Imperial College Press London1999 p.\u2009158.",
      "DOI": "10.1142/p080"
    },
    {
      "key": "e_1_2_1_36_2",
      "first-page": "431",
      "volume": "23",
      "author": "Kobayashi M.",
      "year": "1980",
      "journal-title": "Rep. Prog. Polym. Phys. Jpn."
    },
    {
      "key": "e_1_2_1_37_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1021/ma00161a041"
    },
    {
      "key": "e_1_2_1_38_2",
      "doi-asserted-by": "publisher",
      "DOI": "10.1007/s003960050408"
    }
  ],
  "container-title": "Advanced Functional Materials",
  "original-title": [],
  "language": "en",
  "link": [
    {
      "URL": "https://api.wiley.com/onlinelibrary/tdm/v1/articles/10.1002%2Fadfm.200305034",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "text-mining"
    },
    {
      "URL": "https://onlinelibrary.wiley.com/doi/pdf/10.1002/adfm.200305034",
      "content-type": "unspecified",
      "content-version": "vor",
      "intended-application": "similarity-checking"
    }
  ],
  "deposited": {
    "date-parts": [
      [
        2023,
        11,
        17
      ]
    ],
    "date-time": "2023-11-17T00:47:43Z",
    "timestamp": 1700182063000
  },
  "score": 1,
  "resource": {
    "primary": {
      "URL": "https://onlinelibrary.wiley.com/doi/10.1002/adfm.200305034"
    }
  },
  "subtitle": [],
  "short-title": [],
  "issued": {
    "date-parts": [
      [
        2004,
        9
      ]
    ]
  },
  "references-count": 37,
  "journal-issue": {
    "issue": "9",
    "published-print": {
      "date-parts": [
        [
          2004,
          9
        ]
      ]
    }
  },
  "alternative-id": [
    "10.1002/adfm.200305034"
  ],
  "URL": "http://dx.doi.org/10.1002/adfm.200305034",
  "relation": {},
  "ISSN": [
    "1616-301X",
    "1616-3028"
  ],
  "subject": [],
  "container-title-short": "Adv Funct Materials",
  "published": {
    "date-parts": [
      [
        2004,
        9
      ]
    ]
  }
}